37464-86-1

Basic information

• Product Name: 4-Penten-1-ol,5-phenyl-
• Synonyms: 1-Hydroxy-5-phenylpent-4-ene; 5-Phenyl-4-penten-1-ol
• CAS NO: 37464-86-1
• Molecular Formula: C₁₁H₁₄O
• Molecular Weight: 162.2283
• Mol File: 37464-86-1.mol
• Article Data: 37

Chemical Properties

• Boiling Point: 279.3°Cat760mmHg
• Flash Point: 122.5°C
• Density: 1.008g/cm³
• CAS DataBase Reference: 4-Penten-1-ol,5-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 4-Penten-1-ol,5-phenyl-(37464-86-1)
• EPA Substance Registry System: 4-Penten-1-ol,5-phenyl-(37464-86-1)

Safety Data

• Hazardous Substances Data: 37464-86-1(Hazardous Substances Data)

Upstream product

• 137472-45-8 erythro-2-<1-hydroxy(phenyl)methyl>-1-isopropoxy-1-methylsilacyclopentane 
• 137472-39-0 1-<(Z)-1,2-epoxy-2-phenylethyl>-1-methylsilacyclobutane 
• 100-52-7 benzaldehyde 
• 87436-78-0 (4-hydroxybutyl)-triphenylphosphonium bromide 
• 137472-41-4 erythro-2-hydroxyphenylmethyl-1,1-dimethyl-1-silacyclopentane 
• 137472-41-4 threo-2-hydroxyphenylmethyl-1,1-dimethyl-1-silacyclopentane 
• 93845-04-6 ethyl 5-phenyl-4-pentenoate 
• 1011-61-6 1-phenylpentane-1,5-diol 
• 1392108-21-2 O-(5-phenylpent-4-enyl)-N-benzoyl-N-phenylhydroxylamine 
• 24595-58-2 5-phenylpent-4-yn-1-ol 
• 5390-04-5 pent-1-yn-5-ol 
• 591-50-4 iodobenzene 
• 5371-52-8 2-hydroxytetrahydrofuran 
• 20767-31-1 benzyl(triphenyl)phosphonium bromide 

Downstream Products

• 374094-69-6 (Z)-(5-chloropent-1-en-1-yl)benzene 
• 1070799-24-4 C₂₃H₂₉NO₄S 
• 57238-67-2 (E)-(5-bromopent-1-en-1-yl)benzene 
• 160257-00-1 (Z)-(5-bromopent-1-en-1-yl)benzene 
• 1315320-15-0 C₁₇H₁₇NO₂ 
• 1315320-16-1 C₂₅H₃₁N₃O₆ 
• 1392108-21-2 O-(5-phenylpent-4-enyl)-N-benzoyl-N-phenylhydroxylamine 
• 15212-27-8 2-benzyltetrahydrofuran 
• 99858-43-2 5-phenylpent-4-enylamine 
• 106657-30-1 Acetic acid (R)-phenyl-(R)-tetrahydro-furan-2-yl-methyl ester 

Relevant articles and documents

Organocatalytic, Organic Oxidant Promoted, Enamine C?H Oxidation/Cyclopropanation Reaction

Herein, we demonstrate that organic, single-electron oxidant in the presence of diarylprolinol silylether type catalyst serves as a tool for the transformation of electron-rich enamines to iminium ions. These iminium ions take part in a subsequent Michael-initiated ring-closure (MIRC) reaction with in situ present nucleophile giving rise to overall cyclopropanation reaction of saturated aldehydes. Stereodefined cyclopropanes are obtained in high yields and selectivities. This one-pot transformation represents the additional example of saturated aldehydes being used in the coupled one-pot processes. (Figure presented.).

Rh(I)-catalyzed ring-opening of cyclobutanols via C–C bond activation: Synthesis of cis-olefin with a remote aldehyde

A Rh(I)-catalyzed ring-opening of cyclobutanols has been developed with ring opening products bearing cis-olefin and a remote aldehyde. Various substrates bearing different substituted aryl groups, heterocyclic groups and alkyl groups were compatible with

C(alkenyl)-H Activation via Six-Membered Palladacycles: Catalytic 1,3-Diene Synthesis

A catalytic method to prepare highly substituted 1,3-dienes from two different alkenes is described using a directed, palladium(II)-mediated C(alkenyl)-H activation strategy. The transformation exhibits broad scope across three synthetically useful substrate classes masked with suitable bidentate auxiliaries (4-pentenoic acids, allylic alcohols, and bishomoallylic amines) and tolerates internal nonconjugated alkenes, which have traditionally been a challenging class of substrates in this type of chemistry. Catalytic turnover is enabled by either MnO2 as the stoichiometric oxidant or co-catalytic Co(OAc)2 and O2 (1 atm). Experimental and computational studies were performed to elucidate the preference for C(alkenyl)-H activation over other potential pathways. As part of this effort, a structurally unique alkenylpalladium(II) dimer was isolated and characterized.