38109-73-8Relevant articles and documents
Synthesis of All diastereomers of the piperidine - alkaloid substructure of cyclopamine
Heretsch, Philipp,Rabe, Sebastian,Giannis, Athanasslos
supporting information; experimental part, p. 5410 - 5412 (2010/02/28)
"Chemical Equation Presented" All four diastereomers of the trisubstituted piperidine-alkaloids of the veratramine and jervine type were synthesized with complete stereocontrol starting from enantiopure citronellic acids. The flexible, high-yielding, and scalable route described here will facilitate convergent syntheses and give access to analogues of cyclopamine and other biologically active and diverse steroid alkaloids.