38152-41-9

Upstream product

• 123-11-5 4-methoxy-benzaldehyde 
• 4656-04-6 bis(trimethylsilyl)mercury 
• 75-77-4 chloro-trimethyl-silane 
• 4464-76-0 1,2-bis(4-methoxyphenyl)-1,2-ethanediol 

Downstream Products

• 7677-24-9 trimethylsilyl cyanide 
• 123-11-5 4-methoxy-benzaldehyde 
• 107-46-0 Hexamethyldisiloxane 
• 17258-75-2 Tetrachlorohydroquinone bis(trimethylsilyl) ether 
• 66768-20-5 (R,R)-(+)-1,2-bis(4-methoxyphenyl)ethane-1,2-diol 
• 122798-27-0 (-)-(2S,3S)-1,2-bis(4-methoxyphenyl)ethane1,2-diol 
• 4464-76-0 1,2-bis(4-methoxyphenyl)-1,2-ethanediol 

Relevant academic research and scientific papers

Reaction of (η2-arylaldehyde)nickel(0) complexes with Me3SiX (X=OTf, Cl). Application to catalytic reductive homocoupling reaction of arylaldehyde

Arylaldehydes can coordinate to nickel(0) in η2-fashion to give η2-arylaldehydenickel complexes, which react with Me3SiOTf or Me3SiCl to give η1:η1-siloxybenzylnickel or η3-silox

Ni/Cr/Al multi-metal redox-mediated alkenylation of aldehydes

Alkenylation of aldehydes mediated by a catalytic amount of Cr(II)/Ni(0), using aluminium as an electron source, was performed to afford the corresponding allyl alcohol derivatives in good to moderate yields.

Photoinduced Electron Transfer in Pinacol Cleavage with Quinones via Highly Labile Cation Radicals. Direct Comparison of Charge-Transfer Excitation and Photosensitization

Benzopinacol and related diphenylethane-like donors (D) form electron donor-acceptor (EDA) complexes with chloranil and similar benzoquinones (A), in which the deliberate irradiation of the charge-transfer absorption band (hνCT) leads to oxidative cleavage (retropinacol) via electron transfer.Photosensitization by excitation of the ?-?* band of chloranil and diffusive quenching also effects the C-C bond cleavage of the same donors.The photoefficiencies of both photochemical processes are quantitatively compared with respect to the lifetimes of the pinacol cation radicals (D+ radical), as determined by the competition from back electron transfer and diffusion.These photoinduced processes are considered in the context of electron-transfer for an equivalent thermal reaction which occurs in the dark with high-potential quinones and electron-rich pinacols.

Synthesis of Pinacol Silylethers from Aromatic Aldehydes via α-Siloxybenzyliron Complexes

Quantitative synthesis of pinacol ethers 4, 2 (X = H, Me, OMe or Cl) from the α-siloxybenzyliron complexes, 3 is reported.The iron dimer, 5 was the only other product which was reused for the reaction.