38477-05-3

Upstream product

• 21378-06-3 1-bromo-3-ethylpent-2-ene 
• 124-38-9 carbon dioxide 
• 42998-18-5 ethyl 2,2-diethylbut-3-enoate 
• 99851-11-3 ethyl 2,2-diethyl-3-hydroxybutyrate 
• 2983-38-2 ethyl 2-ethylbutanoate 
• 936724-71-9 ethyl 2,2-diethyl-3-(toluene-4-sulfonyloxy)butyrate 
• 761-20-6 1-chloro-3-ethylpent-2-ene 

Downstream Products

• 852102-05-7 N-{2-bromo-4-[(trifluoromethyl)oxy]phenyl}-2,2-diethylbut-3-enamide 
• 852102-04-6 N-[2-bromo-4-(trifluoromethyl)phenyl]-2,2-diethylbut-3-enamide 
• 852102-01-3 N-(2-bromo-4-methoxyphenyl)-2,2-diethylbut-3-enamide 
• 852102-03-5 N-(2-bromo-4-fluorophenyl)-2,2-diethylbut-3-enamide 
• 852102-02-4 N-(2-bromo-4-methylphenyl)-2,2-diethylbut-3-enamide 
• 852101-99-6 N-(2-bromophenyl)-2,2-diethylbut-3-enamide 

Relevant academic research and scientific papers

Regioselective synthesis of 3,3-diethyl-4-(methylene)-1-quinol-2-ones by an intramolecular microwave assisted heck reaction

A protocol for the intramolecular Heck cyclization to afford 3,3-diethyl-4-(methylene)-1-quinol-2-ones is described. We observed that the use of microwave irradiation increased the efficiency of the reaction. Several examples are presented which show the

Regioselective Synthesis of β,γ-Unsaturated Acids by the Electrochemical Carboxylation of Allylic Bromides Using a Reactive-metal Anode

Electrolysis of γ-mono and disubstituted allylic bromides in the presence of atmospheric pressure of carbon dioxide using a platinum cathode and a magnesium anode gave regioselectively the corresponding γ-mono and disubstituted β,γ-unsaturated carboxylic acids in 34-71percent yields.