Welcome to LookChem.com Sign In|Join Free
  • or

91-63-4

Post Buying Request

91-63-4 Suppliers

Recommended suppliersmore

Product FOB Price Min.Order Supply Ability Supplier
Quinaldine
Cas No: 91-63-4
USD $ 3.0-3.0 / Kilogram 1 Kilogram 1-100 Metric Ton/Month Dayang Chem (Hangzhou) Co.,Ltd. Contact Supplier
High purity Various Specifications Quinaldine CAS: 91-63-4
Cas No: 91-63-4
USD $ 100.0-500.0 / Gram 1 Gram 99999 Gram/Year Hangzhou Dingyan Chem Co., Ltd Contact Supplier
High quality Quinaldine supplier in China
Cas No: 91-63-4
No Data No Data Metric Ton/Day Simagchem Corporation Contact Supplier
2-Methylquinoline
Cas No: 91-63-4
No Data 1 Kilogram 20 Metric Ton/Week Henan Allgreen Chemical Co.,Ltd Contact Supplier
Factory Supply 2-methylquinoline
Cas No: 91-63-4
No Data 1 1 Ality Chemical Corporation Contact Supplier
Quinaldine
Cas No: 91-63-4
No Data 10 Milligram Amadis Chemical Co., Ltd. Contact Supplier
Quinaldine CAS: 91-63-4
Cas No: 91-63-4
USD $ 1.0-2.0 / Metric Ton 5 Metric Ton 1000 Metric Ton/Year Henan Sinotech Import&Export Corporation Contact Supplier
Intermediates 2-Methyl Quinoline CAS No. 91-63-4
Cas No: 91-63-4
No Data 100 Gram 20000 Kilogram/Day Hubei XinRunde Chemical Co., Ltd Contact Supplier
CAS No.91-63-4 Quinaldine
Cas No: 91-63-4
No Data 1 Kilogram 30 Metric Ton/Month Henan Tianfu Chemical Co., Ltd. Contact Supplier
CAS NO.:91-63-4
Cas No: 91-63-4
No Data No Data 10000 Metric Ton/Month Henan Wentao Chemical Product Co., Ltd. Contact Supplier

91-63-4 Usage

Hazard

Strong irritant to mucous membranes.

Synthesis Reference(s)

Journal of Heterocyclic Chemistry, 13, p. 1279, 1976 DOI: 10.1002/jhet.5570130626The Journal of Organic Chemistry, 52, p. 3847, 1987 DOI: 10.1021/jo00226a023Synthesis, p. 324, 1996 DOI: 10.1055/s-1996-4221

Uses

A useful ingredient in anti-malaria drugs, in manufacturing dyes, food colorants , pharmaceuticals and pH indicators.

Definition

ChEBI: A quinoline compound in which the quinoline skeleton is substituted at C-2 with a methyl group.

General Description

A colorless oily liquid darkening to red-brown on exposure to air. Flash point 175°F. Denser than water and slightly soluble in water. Vapors heavier than air. Produces toxic oxides of nitrogen during combustion. Used to make dyes, pharmaceuticals and other chemicals.

Chemical Properties

yellowish-brown liquid

Air & Water Reactions

Slightly soluble in water.

Reactivity Profile

Quinaldine neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides. Keep tightly closed and protected from light .

Purification Methods

Dry it with Na2SO4 or by refluxing with BaO, then fractionally distil it under reduced pressure and redistil it from zinc dust. Purify it further by conversion to its phosphate (m 220o) or picrate (m 192o) from which after recrystallisation, the free base is regenerated. [Packer et al. J Am Chem Soc 80 905 1958.] Its ZnCl2 complex can be used for the same purpose. [Beilstein 20 III/IV 3454, 20 V 375.]

Fire Hazard

Quinaldine is probably combustible.

91-63-4 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
Alfa Aesar (A13412)  Quinaldine, 97+%    91-63-4 25g 215.0CNY Detail
Alfa Aesar (A13412)  Quinaldine, 97+%    91-63-4 100g 524.0CNY Detail
Alfa Aesar (A13412)  Quinaldine, 97+%    91-63-4 500g 2086.0CNY Detail
Aldrich (22550)  Quinaldine  ≥95.0% (GC) 91-63-4 22550-250ML-F 995.67CNY Detail
Aldrich (22550)  Quinaldine  ≥95.0% (GC) 91-63-4 22550-1L-F 2,676.96CNY Detail
Sigma-Aldrich (Q2125)  Quinaldine  analytical standard, ≥90% (GC) 91-63-4 Q2125-500ML 1,113.84CNY Detail
Sigma-Aldrich (Q2125)  Quinaldine  analytical standard, ≥90% (GC) 91-63-4 Q2125-1L 2,163.33CNY Detail

91-63-4SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name 2-Methylquinoline

1.2 Other means of identification

Product number -
Other names Quinoline, 2-methyl-

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:91-63-4 SDS

91-63-4Synthetic route

2-n-butylquinoline
7661-39-4

2-n-butylquinoline

A

2-methylquinoline
91-63-4

2-methylquinoline

B

propene
187737-37-7

propene

Conditions
ConditionsYield
In benzene Ambient temperature; Irradiation;A 100%
B 100%
2-quinolin-2-yl-ethanol
1011-50-3

2-quinolin-2-yl-ethanol

A

2-methylquinoline
91-63-4

2-methylquinoline

B

formaldehyd
50-00-0

formaldehyd

Conditions
ConditionsYield
In benzene Ambient temperature; Irradiation;A 100%
B 100%
2-methyl-1,2,3,4-tetrahydroquinolin-4-yl-(phenyl)amine
1026-05-7

2-methyl-1,2,3,4-tetrahydroquinolin-4-yl-(phenyl)amine

A

2-methylquinoline
91-63-4

2-methylquinoline

B

aniline
62-53-3

aniline

Conditions
ConditionsYield
With palladium dichloride In acetonitrileA 100%
B 100%
2-methyl-1,2-dihydroquinoline
1125-81-1

2-methyl-1,2-dihydroquinoline

2-methylquinoline
91-63-4

2-methylquinoline

Conditions
ConditionsYield
Stage #1: 2-methyl-1,2-dihydroquinoline With sodium hydroxide In ethanol at 20℃; for 0.5h; Inert atmosphere; Schlenk technique; Irradiation;
Stage #2: With tris(bipyridine)ruthenium(II) dichloride hexahydrate; chloropyridinecobaloxime(III) In ethanol at 20℃; for 1h;
99%
With tris(bipyridine)ruthenium(II) dichloride hexahydrate; Co(dmgH)2(4-MeCO2Py)Cl In water at 28℃; for 4h; Mechanism; Schlenk technique; Inert atmosphere; Irradiation;91%
With arsenic(V) oxide
With bis(1,5-cyclooctadiene)diiridium(I) dichloride; iodine; (S)-(-)-(6,6’-dimethoxybiphenyl-2,2’-diyl)bis(diphenylphosphine) In toluene at 20℃;
With rose bengal; oxygen; potassium carbonate In N,N-dimethyl acetamide at 20℃; for 12h; Irradiation;
1,2,3,4-tetrahydro-2-methylquinoline
1780-19-4

1,2,3,4-tetrahydro-2-methylquinoline

2-methylquinoline
91-63-4

2-methylquinoline

Conditions
ConditionsYield
With tris(bipyridine)ruthenium(II) dichloride hexahydrate; chloropyridinecobaloxime(III) In ethanol at 30℃; for 6h; Reagent/catalyst; Solvent; Schlenk technique; Inert atmosphere; Irradiation;99%
With 6C44H32N6O4Ru(2+)*12Hf(2+)*8O(2-)*14HO(1-)*6C16H22ClCoN5O6(1-) In 2,2,2-trifluoroethanol; acetonitrile at 20℃; for 24h; Catalytic behavior; Inert atmosphere; Irradiation;99%
With isolated cobalt single atom sites stabilized on an ordered porous nitrogen doped carbon matrix In 1,3,5-trimethyl-benzene at 120℃; for 8h; Schlenk technique;96%
(E)-4-(2-aminophenyl)but-3-en-2-one
265990-67-8

(E)-4-(2-aminophenyl)but-3-en-2-one

2-methylquinoline
91-63-4

2-methylquinoline

Conditions
ConditionsYield
In tetrahydrofuran for 12h; Irradiation;99%
In ethanol at 30℃; Concentration; Solvent; UV-irradiation; Flow reactor;91%
In benzene for 0.366667h; Irradiation;74%
6-chloro-2-methylquinoline
92-46-6

6-chloro-2-methylquinoline

2-methylquinoline
91-63-4

2-methylquinoline

Conditions
ConditionsYield
With methylene chloride; tetra-(n-butyl)ammonium iodide In N,N-dimethyl-formamide electrolysis, -2.0 V;90%
1,1,2,2-Tetraphenyl-ethane-1,2-diol; compound with 2-methyl-quinoline
102102-32-9

1,1,2,2-Tetraphenyl-ethane-1,2-diol; compound with 2-methyl-quinoline

2-methylquinoline
91-63-4

2-methylquinoline

Conditions
ConditionsYield
at 120℃; under 5 Torr;90%
trans-Crotonaldehyde
123-73-9

trans-Crotonaldehyde

aniline
62-53-3

aniline

2-methylquinoline
91-63-4

2-methylquinoline

Conditions
ConditionsYield
With phospho-tungstic acid; phosphotungstic acid; silica gel for 0.166667h; Doebner-Miller reaction; microwave irradiation;90%
With hydrogenchloride; chloranil In butan-1-ol for 0.333333h; Heating;
acetone
67-64-1

acetone

2-nitro-benzaldehyde
552-89-6

2-nitro-benzaldehyde

2-methylquinoline
91-63-4

2-methylquinoline

Conditions
ConditionsYield
With 4 A molecular sieve; tin(ll) chloride; zinc(II) chloride In ethanol at 70℃;90%
Stage #1: acetone; 2-nitro-benzaldehyde With zinc(II) chloride In methanol at 67℃; for 1h; Inert atmosphere; Molecular sieve;
Stage #2: With tin(ll) chloride In methanol for 12h; Inert atmosphere; Molecular sieve;
90%
With Li*4.5 THF In methanol at 20 - 25℃; for 63h;77%
β-anilinocrotonaldehyde
106237-27-8

β-anilinocrotonaldehyde

2-methylquinoline
91-63-4

2-methylquinoline

Conditions
ConditionsYield
With sulfuric acid for 48h; Ambient temperature;89%
With sulfuric acid at 25℃; Rate constant;
4-phenyl-2-butanone oxime
66417-92-3, 104260-82-4, 6944-54-3

4-phenyl-2-butanone oxime

A

2-methylquinoline
91-63-4

2-methylquinoline

B

methyl-N-(benzyl-methyl)-formamide
877-95-2

methyl-N-(benzyl-methyl)-formamide

Conditions
ConditionsYield
With trifluorormethanesulfonic acid; tetrabutylammonium perrhenate In nitromethane Heating;A 7%
B 88%
2-methyl-1,2,3,4-tetrahydroquinolin-4-yl-(phenyl)amine
1026-05-7

2-methyl-1,2,3,4-tetrahydroquinolin-4-yl-(phenyl)amine

2-methylquinoline
91-63-4

2-methylquinoline

Conditions
ConditionsYield
With N-hydroxy-3,4,5,6-tetrachlorophthalimide; 5,6-bis(5-methoxythiophen-2-yl)pyrazine-2,3-dicarbonitrile In acetonitrile at 25℃; for 5h; Irradiation; Green chemistry;88%
With 5,6-bis(5-methoxythiophen-2-yl)pyrazine-2,3-dicarbonitrile; C9H3Cl4NO2 In N,N-dimethyl acetamide; acetonitrile at 25℃; for 3h; Solvent; Irradiation;81%
ethanol
64-17-5

ethanol

carbon monoxide
201230-82-2

carbon monoxide

aniline
62-53-3

aniline

A

2-methylquinoline
91-63-4

2-methylquinoline

B

N-carboethoxyaniline
101-99-5

N-carboethoxyaniline

C

bis(diphenyl)urea
102-07-8

bis(diphenyl)urea

Conditions
ConditionsYield
With oxygen; rhodium contaminated with carbon at 160 - 170℃; under 63253.7 Torr; for 3h; Mechanism; Product distribution; further catalyst systems; other amines;A n/a
B 86%
C 1.5%
2-Chloroquinoline
612-62-4

2-Chloroquinoline

methylmagnesium bromide
75-16-1

methylmagnesium bromide

2-methylquinoline
91-63-4

2-methylquinoline

Conditions
ConditionsYield
With copper(I) bromide In tetrahydrofuran; diethyl ether 1.) -78 degC, 3h, 2.) RT, overnight;85%
With copper(I) bromide In tetrahydrofuran at -78 - 20℃; Product distribution; other heteroaryl halides and cuprous salts as catalysts;85%
Stage #1: methylmagnesium bromide With iron(III) trifluoride; N,N′-bis(2,6-diisopropylphenyl)imidazol-2-ylidene hydrochloride In tetrahydrofuran at 0℃; Inert atmosphere;
Stage #2: 2-Chloroquinoline In tetrahydrofuran at 20 - 60℃; for 26h; Inert atmosphere;
40%
Stage #1: methylmagnesium bromide With iron(III) trifluoride; 1,3-bis[(2,6-diisopropyl)phenyl]imidazolinium chloride In tetrahydrofuran at 0℃; Inert atmosphere;
Stage #2: 2-Chloroquinoline In tetrahydrofuran at 60℃; for 26h; Inert atmosphere; chemoselective reaction;
40%
Quinoline N-oxide
1613-37-2

Quinoline N-oxide

4,4,5,5-tetramethyl-2-[(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)methyl]-1,3,2-dioxaborolane
78782-17-9

4,4,5,5-tetramethyl-2-[(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)methyl]-1,3,2-dioxaborolane

2-methylquinoline
91-63-4

2-methylquinoline

Conditions
ConditionsYield
With sodium methylate In toluene at 80℃; for 3h; Catalytic behavior; Reagent/catalyst; Solvent; Temperature; regioselective reaction;85%
4-(2-aminophenyl)-2-butanol
457622-20-7

4-(2-aminophenyl)-2-butanol

A

2-methylquinoline
91-63-4

2-methylquinoline

B

1,2,3,4-tetrahydro-2-methylquinoline
1780-19-4

1,2,3,4-tetrahydro-2-methylquinoline

Conditions
ConditionsYield
With bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]; potassium carbonate In toluene at 111℃; for 20h;A 9%
B 83%
4-chloro-2-methylquinoline
4295-06-1

4-chloro-2-methylquinoline

2-methylquinoline
91-63-4

2-methylquinoline

Conditions
ConditionsYield
With iron(III)-acetylacetonate; tert-butylmagnesium chloride In tetrahydrofuran at 20℃; for 1.5h; Inert atmosphere;82%
With hydrogen iodide; acetic acid at 250 - 270℃;
1-(2'-Acetamino-phenyl)-ethanol
89937-05-3

1-(2'-Acetamino-phenyl)-ethanol

2-methylquinoline
91-63-4

2-methylquinoline

Conditions
ConditionsYield
With PPA at 210℃; for 20h;82%
N-[2-((E)-3-Oxo-but-1-enyl)-phenyl]-acetamide
72592-66-6

N-[2-((E)-3-Oxo-but-1-enyl)-phenyl]-acetamide

2-methylquinoline
91-63-4

2-methylquinoline

Conditions
ConditionsYield
With silver hexafluoroantimonate; [RhCl2(p-cymene)]2; copper(II) acetate monohydrate; acetic acid In tetrahydrofuran at 120℃; for 12h; Inert atmosphere; Sealed tube;81%
With hydrogenchloride for 0.05h; Heating;93 mg
ethanol
64-17-5

ethanol

nitrobenzene
98-95-3

nitrobenzene

2-methylquinoline
91-63-4

2-methylquinoline

Conditions
ConditionsYield
With silver tetrafluoroborate; oxygen; palladium diacetate; Trimethylacetic acid at 180℃; for 24h; Temperature; Reagent/catalyst;81%
With gold on titanium oxide for 5h; Irradiation;75%
With titania-supported iridium nanoclusters at 120℃; under 3800.26 Torr; for 28h; Autoclave; Inert atmosphere;74%
With MoS1.73O0.1 at 190℃; for 4h; Reagent/catalyst;72%
Stage #1: ethanol; nitrobenzene With MoS1.73O0.1; hydrogen In toluene at 160℃; for 8h;
Stage #2: In toluene at 150℃; for 6h; Temperature; Solvent; Reagent/catalyst;
70%
2-methylquinoline
91-63-4

2-methylquinoline

1,2,3,4-tetrahydro-2-methylquinoline
1780-19-4

1,2,3,4-tetrahydro-2-methylquinoline

Conditions
ConditionsYield
With [1-butyl-2,3-dimethylimidazolium][tppm] stabilized rhodium nanoarticles at 50℃; under 22502.3 Torr; for 5h; Ionic liquid; Autoclave; chemoselective reaction;100%
With hydrogen at 50℃; under 22502.3 Torr; for 10h; Autoclave; Sealed tube; Ionic liquid; chemoselective reaction;100%
With [2,2]bipyridinyl; formic acid; dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; sodium formate In water at 80℃; for 1h; pH=3.5;99%
2-methylquinoline
91-63-4

2-methylquinoline

2-methylquinoline-4-carboxamide
15821-13-3

2-methylquinoline-4-carboxamide

Conditions
ConditionsYield
With sulfuric acid; dihydrogen peroxide; titanium(IV) oxide for 5h; sunlight irradiation;100%
With sulfuric acid; dihydrogen peroxide; iron(II) sulfate at 60℃; for 4h;100 % Turnov.
With N-hydroxyphthalimide; ammonium cerium(IV) nitrate; trifluoroacetic acid at 70℃; for 6h;
2-methylquinoline
91-63-4

2-methylquinoline

terephthalaldehyde,
623-27-8

terephthalaldehyde,

Conditions
ConditionsYield
With acetic anhydride for 6h; Reflux;100%
With acetic anhydride for 6h; Reflux;100%
2-methylquinoline
91-63-4

2-methylquinoline

4-nitrobenzaldehdye
555-16-8

4-nitrobenzaldehdye

A

4-nitrobenzyl chloride
619-73-8

4-nitrobenzyl chloride

B

1,2,3,4-tetrahydro-2-methylquinoline
1780-19-4

1,2,3,4-tetrahydro-2-methylquinoline

Conditions
ConditionsYield
With (7,8-benzoquinolinato)hydrido(aqua)bis(triphenylphosphine)iridium(III) tetrakis[3,5-bis(trifluoromethyl)phenyl]borate; hydrogen In toluene at 80℃; for 18h;A 100%
B 78%
2-methylquinoline
91-63-4

2-methylquinoline

p-formylacetophenone
3457-45-2

p-formylacetophenone

A

4-(hydroxymethyl)acetophenone
75633-63-5

4-(hydroxymethyl)acetophenone

B

1,2,3,4-tetrahydro-2-methylquinoline
1780-19-4

1,2,3,4-tetrahydro-2-methylquinoline

Conditions
ConditionsYield
With (7,8-benzoquinolinato)hydrido(aqua)bis(triphenylphosphine)iridium(III) tetrakis[3,5-bis(trifluoromethyl)phenyl]borate; hydrogen In toluene at 80℃; for 18h;A 100%
B 100%
chromium(VI) oxide

chromium(VI) oxide

2-methylquinoline
91-63-4

2-methylquinoline

hydrogen fluoride
7664-39-3

hydrogen fluoride

quinaldinium fluorochromate(VI)
166265-09-4

quinaldinium fluorochromate(VI)

Conditions
ConditionsYield
Stage #1: chromium(VI) oxide; hydrogen fluoride In water
Stage #2: 2-methylquinoline In water for 1h;
99.4%
2-methylquinoline
91-63-4

2-methylquinoline

formic acid
64-18-6

formic acid

2-methyl-3,4-dihydroquinoline-1(2H)-carbaldehyde
27850-49-3

2-methyl-3,4-dihydroquinoline-1(2H)-carbaldehyde

Conditions
ConditionsYield
With nitrogen modified cobalt nanoparticles supported on carbon In toluene at 130℃;99%
With isolated cobalt single atom sites stabilized on an ordered porous nitrogen doped carbon matrix In toluene at 120℃; for 1.5h; Schlenk technique;96%
With sodium formate In water at 80℃; for 24h; pH=4.5; Schlenk technique; Inert atmosphere;90%
2-methylquinoline
91-63-4

2-methylquinoline

m-bromobenzoic aldehyde
3132-99-8

m-bromobenzoic aldehyde

(E)-2-(3-bromostyryl)quinoline

(E)-2-(3-bromostyryl)quinoline

Conditions
ConditionsYield
With iron(II) acetate; trifluoroacetic acid In toluene at 100℃; for 24h; Inert atmosphere; Schlenk technique; Green chemistry;99%
In water at 120℃; for 36h; Sealed tube;94%
In 1,4-dioxane at 140℃; for 48h; Autoclave; Green chemistry;89%
With zinc(II) chloride
2-methylquinoline
91-63-4

2-methylquinoline

3-nitro-benzaldehyde
99-61-6

3-nitro-benzaldehyde

3-[2-(quinolin-2-yl)ethenyl]nitrobenzene
38101-92-7

3-[2-(quinolin-2-yl)ethenyl]nitrobenzene

Conditions
ConditionsYield
With lanthanum pentafluorobenzoate In toluene at 120℃; for 24h;99%
With iron(II) acetate; trifluoroacetic acid In toluene at 100℃; for 24h; Inert atmosphere; Schlenk technique; Green chemistry;90%
With acetic anhydride In water88%
2-methylquinoline
91-63-4

2-methylquinoline

4-nitrobenzaldehdye
555-16-8

4-nitrobenzaldehdye

2-[(E)-2-(4-nitrophenyl)ethenyl]quinoline
38101-93-8

2-[(E)-2-(4-nitrophenyl)ethenyl]quinoline

Conditions
ConditionsYield
With lanthanum pentafluorobenzoate In toluene at 120℃; for 24h;99%
With tert-butylammonium hexafluorophosphate(V); calcium(II) trifluoromethanesulfonate In neat (no solvent) at 130℃; Green chemistry;98%
With iron(II) acetate; trifluoroacetic acid In toluene at 100℃; for 24h; Inert atmosphere; Schlenk technique; Green chemistry;92%
2-methylquinoline
91-63-4

2-methylquinoline

(R)-1,2,3,4-tetrahydroquinaldine
1780-19-4, 63430-95-5, 74497-74-8

(R)-1,2,3,4-tetrahydroquinaldine

Conditions
ConditionsYield
With bis(1,5-cyclooctadiene)diiridium(I) dichloride; (R)-(+)-2,2',6,6'-tetramethoxy-4,4'-bis(diphenylphosphino)-3,3'-bipyridine; hydrogen; iodine In tetrahydrofuran at 20℃; under 36201.3 Torr; for 24h; Autoclave; optical yield given as %ee; enantioselective reaction;99%
With (R)-(-)-5,5’-bis(diphenyl;phosphine)-2,2,2’,2’-tetrafluoro-4,4’-bi-1,3-benzodioxole; bis(1,5-cyclooctadiene)diiridium(I) dichloride; hydrogen; iodine In tetrahydrofuran at 20℃; under 36201.3 Torr; for 24h; Autoclave; optical yield given as %ee; enantioselective reaction;99%
With C34H39F3N2O5RuS2; hydrogen In methanol at 25℃; under 38002.6 Torr; for 14h; Autoclave; optical yield given as %ee; enantioselective reaction;99%
2-methylquinoline
91-63-4

2-methylquinoline

chromium(0) hexacarbonyl
199620-14-9, 13007-92-6

chromium(0) hexacarbonyl

pentacarbonyl(η(1)-quinaldine)chromium(0)
222291-39-6

pentacarbonyl(η(1)-quinaldine)chromium(0)

Conditions
ConditionsYield
In tetrahydrofuran; dibutyl ether Ar-atmosphere; heating equimolar amts. to 130°C for 9 h (in Bu2O/THF=10:1); cooling to room temp., filtration (Celite), evapn.;99%
In tetrahydrofuran Irradiation (UV/VIS); Ar-atmosphere; irradiation of Cr-complex soln. (Hg lamp, λ=253 nm, room temp., 80 h), stirring with excess of ligand (room temp., 24 h); evapn. (vac.);60%
2-methylquinoline
91-63-4

2-methylquinoline

trans-chloromethylbis(dimethylsulfoxide)platinum(II)
185226-19-1, 70424-04-3

trans-chloromethylbis(dimethylsulfoxide)platinum(II)

trans(C,N)-chloromethyl(dimethyl sulfoxide)(2-methylquinoline)platinum(II)
185043-01-0

trans(C,N)-chloromethyl(dimethyl sulfoxide)(2-methylquinoline)platinum(II)

Conditions
ConditionsYield
In dichloromethane stirring stoich. amts. for 30 min; addn. of pentane, pptn. on cooling, collection (filtration), washing (cold pentane), drying (vac.); elem. anal.;99%
4-Cyanochlorobenzene
623-03-0

4-Cyanochlorobenzene

2-methylquinoline
91-63-4

2-methylquinoline

2-(quinolyul-2-yl)-1-(4-chlorophenyl)-1-ethenamine

2-(quinolyul-2-yl)-1-(4-chlorophenyl)-1-ethenamine

Conditions
ConditionsYield
Stage #1: 2-methylquinoline With lithium diisopropyl amide In tetrahydrofuran; hexane at -70℃; for 1h;
Stage #2: 4-Cyanochlorobenzene In tetrahydrofuran; hexane at -70 - 20℃; for 2h; Further stages.;
99%
2-methylquinoline
91-63-4

2-methylquinoline

(S)-2-methyl-1,2,3,4-tetrahydroquinoline
200125-70-8

(S)-2-methyl-1,2,3,4-tetrahydroquinoline

Conditions
ConditionsYield
With C32H34F6IrN2O5S2; hydrogen; trifluoroacetic acid In methanol at 15℃; under 38002.6 Torr; for 24h; optical yield given as %ee; enantioselective reaction;99%
With Ru(trifluoromethanesulfonate)(N-(p-toluenesulfonyl)-1,2-diphenylethylenediamine)(η6-cymene); hydrogen at 25℃; under 38002.6 Torr; Autoclave; Neat (no solvent); optical yield given as %ee; enantioselective reaction;99%
With bis(1,5-cyclooctadiene)diiridium(I) dichloride; (S)-6,6'-bis(diphenylphosphino)-1,1'-biphenyl-2,2'-diylbis(trifluoromethylsulfonate); hydrogen; iodine In tetrahydrofuran at 20℃; under 36201.3 Torr; for 22h; Inert atmosphere; Autoclave; optical yield given as %ee; enantioselective reaction;99%
4-Cyanochlorobenzene
623-03-0

4-Cyanochlorobenzene

2-methylquinoline
91-63-4

2-methylquinoline

2-(quinolin-2-yl)-1-(4-chlorophenyl)-1-ethenamine
1045335-58-7

2-(quinolin-2-yl)-1-(4-chlorophenyl)-1-ethenamine

Conditions
ConditionsYield
Stage #1: 2-methylquinoline With n-butyllithium; diisopropylamine In tetrahydrofuran at -70℃; for 1h; Inert atmosphere;
Stage #2: 4-Cyanochlorobenzene In tetrahydrofuran at -70 - 20℃; Inert atmosphere;
Stage #3: With water In tetrahydrofuran
99%
2-methylquinoline
91-63-4

2-methylquinoline

1,1,1-trifluoroacetophenone
434-45-7

1,1,1-trifluoroacetophenone

1,1,1-trifluoro-2-phenyl-3-(quinolin-2-yl)propan-2-ol
1419293-70-1

1,1,1-trifluoro-2-phenyl-3-(quinolin-2-yl)propan-2-ol

Conditions
ConditionsYield
With indium(III) chloride In tert-butyl alcohol at 60℃; for 24h; Reagent/catalyst; Solvent;99%
With iron(II) perchlorate monohydrate In dimethyl sulfoxide at 60℃; for 24h; Catalytic behavior; Solvent; Temperature; Sealed tube;93%
With ytterbium(III) triflate In 1,4-dioxane at 110℃; for 12h;90%
2-methylquinoline
91-63-4

2-methylquinoline

N-(p-chlorobenzyl)aniline
4750-61-2

N-(p-chlorobenzyl)aniline

(E)-2-(4-chlorostyryl)quinoline
38101-91-6

(E)-2-(4-chlorostyryl)quinoline

Conditions
ConditionsYield
Stage #1: N-(p-chlorobenzyl)aniline With 2,3-dicyano-5,6-dichloro-p-benzoquinone In N,N-dimethyl-formamide at 20℃; for 0.0833333h; Inert atmosphere;
Stage #2: 2-methylquinoline In N,N-dimethyl-formamide at 70℃; for 24h; Inert atmosphere; diastereoselective reaction;
99%
2-methylquinoline
91-63-4

2-methylquinoline

benzylidene phenylamine
538-51-2

benzylidene phenylamine

2-[(E)-styryl]quinoline
38101-69-8

2-[(E)-styryl]quinoline

Conditions
ConditionsYield
With 2,3-dichloro-5,6-dicyanohydroquinone In N,N-dimethyl-formamide at 70℃; for 24h; Inert atmosphere; diastereoselective reaction;99%
2-methylquinoline
91-63-4

2-methylquinoline

N-(3-methoxybenzyl)aniline
81308-21-6

N-(3-methoxybenzyl)aniline

(E)-2-(3-methoxystyryl)quinoline
1289213-22-4

(E)-2-(3-methoxystyryl)quinoline

Conditions
ConditionsYield
Stage #1: N-(3-methoxybenzyl)aniline With 2,3-dicyano-5,6-dichloro-p-benzoquinone In N,N-dimethyl-formamide at 20℃; for 0.0833333h; Inert atmosphere;
Stage #2: 2-methylquinoline In N,N-dimethyl-formamide at 70℃; for 24h; Inert atmosphere; diastereoselective reaction;
99%
2-methylquinoline
91-63-4

2-methylquinoline

N-(m-chlorobenzyl)aniline
10359-19-0

N-(m-chlorobenzyl)aniline

(E)-2-(3-chlorostyryl)quinoline
1318193-02-0

(E)-2-(3-chlorostyryl)quinoline

Conditions
ConditionsYield
Stage #1: N-(m-chlorobenzyl)aniline With 2,3-dicyano-5,6-dichloro-p-benzoquinone In N,N-dimethyl-formamide at 20℃; for 0.0833333h; Inert atmosphere;
Stage #2: 2-methylquinoline In N,N-dimethyl-formamide at 70℃; for 24h; Inert atmosphere; diastereoselective reaction;
99%
2-methylquinoline
91-63-4

2-methylquinoline

N-(2-methoxybenzyl)aniline
77664-18-7

N-(2-methoxybenzyl)aniline

2'-methoxy-2-trans-styrylquinoline

2'-methoxy-2-trans-styrylquinoline

Conditions
ConditionsYield
Stage #1: N-(2-methoxybenzyl)aniline With 2,3-dicyano-5,6-dichloro-p-benzoquinone In N,N-dimethyl-formamide at 20℃; for 0.0833333h; Inert atmosphere;
Stage #2: 2-methylquinoline In N,N-dimethyl-formamide at 70℃; for 24h; Inert atmosphere; diastereoselective reaction;
99%
2-methylquinoline
91-63-4

2-methylquinoline

N-(thiophen-2-ylmethyl)aniline
40625-28-3

N-(thiophen-2-ylmethyl)aniline

(E)-2-(2-(thiophen-2-yl)ethenyl)quinoline
73010-95-4

(E)-2-(2-(thiophen-2-yl)ethenyl)quinoline

Conditions
ConditionsYield
Stage #1: N-(thiophen-2-ylmethyl)aniline With 2,3-dicyano-5,6-dichloro-p-benzoquinone In N,N-dimethyl-formamide at 20℃; for 0.0833333h; Inert atmosphere;
Stage #2: 2-methylquinoline In N,N-dimethyl-formamide at 70℃; for 24h; Inert atmosphere; diastereoselective reaction;
99%
2-methylquinoline
91-63-4

2-methylquinoline

N-Benzylaniline
758640-21-0

N-Benzylaniline

2-[(E)-styryl]quinoline
38101-69-8

2-[(E)-styryl]quinoline

Conditions
ConditionsYield
Stage #1: N-Benzylaniline With 2,3-dicyano-5,6-dichloro-p-benzoquinone In N,N-dimethyl-formamide at 20℃; for 0.0833333h; Inert atmosphere;
Stage #2: 2-methylquinoline In N,N-dimethyl-formamide at 70℃; for 24h; Reagent/catalyst; Solvent; Temperature; Time; Inert atmosphere; diastereoselective reaction;
99%
Post a RFQ

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1

What can I do for you?
Get Best Price

Get Best Price for 91-63-4