39033-45-9Relevant articles and documents
A vanadium-based chemical oscillator: Identification of chemical species responsible for the redox reaction and construction of a simplified model
Kanamori, Kan,Kataoka, Hiroshi,Matsugo, Seiichi
, p. 4570 - 4573 (2013/01/15)
To identify the chemical species involved in a unique, vanadium-based chemical oscillator reaction, products derived from indole in the oscillation solution were isolated and characterized. NMR and mass spectra showed that 3,3-dichloro-2-oxoindole and isatin were formed during the oscillation process. The formation of these two compounds suggests that peroxo species such as CHCl2OO· and CHCl2OOH play a key role in the construction of the oscillation system. A skeletal model for the system is proposed based on these findings. Copyright