39161-19-8Relevant academic research and scientific papers
Insights into the activity, selectivity and stability of heterogeneous catalysts in the continuous flow hydroconversion of furfural
Garcia-Olmo, Antonio J.,Yepez, Alfonso,Balu, Alina M.,Romero, Antonio A.,Li, Yingwei,Luque, Rafael
, p. 4705 - 4711 (2016/07/11)
The continuous flow hydroconversion of furfural to a range of furanic derivatives was carried out using a range of metal-containing heterogeneous catalysts in order to provide insights into the reaction pathways for the hydrogenation of furfural. Most of the catalysts used provided excellent furfural conversion (>60%) and varying selectivities to products at mild temperatures (90 °C), including furfuryl alcohol (FA), 2-methylfuran (2-MF), 2-methyltetrahydrofuran (2-MTHF) and furanic intermediates, depending on the flow conditions and the investigated catalyst.
Hydrogenation of allyl alcohols catalyzed by aqueous palladium and platinum nanoparticles
Di Pietrantonio, Krystel,Coccia, Francesca,Tonucci, Lucia,D'Alessandro, Nicola,Bressan, Mario
, p. 68493 - 68499 (2015/09/01)
A series of Pd and Pt nanoparticles (NPs) was prepared starting from the corresponding metal ions and lignosulphonates; NPs were tested as catalysts for allyl alcohols hydrogenation in water at room temperature and pressure. All NPs were active with sharp differences in conversions and selectivities: Pt NPs formed mainly saturated alcohols, whereas Pd NPS were more active, but less selective, forming, in addition to saturated alcohols, also isomeric unsaturated alcohols and aldehydes, both saturated and unsaturated.
New reactions of anticancer-platinum complexes and their intriguing behaviour under various experimental conditions
Aleman, Jose,Del Solar, Virginia,Cubo, Leticia,Quiroga, Adoracion G.,Navarro Ranninger, Carmen
experimental part, p. 10601 - 10607 (2011/01/05)
The anticancer platinum complexes here described react with organic substrates (such as acids, alkenes, alkynes) and catalyze transformations that can occur in biomolecules which contain unsaturated functions. We have analyzed the role of the platinum complexes in the observed reactions and studied the progress of the detected transformations upon variation of the reaction conditions. The Royal Society of Chemistry 2010.
Processes for producing unsaturated alcohols
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Example 1, (2008/06/13)
This invention relates in part to processes for producing one or more substituted or unsubstituted unsaturated alcohols which comprise reacting one or more substituted or unsubstituted alkadienes with carbon monoxide and hydrogen in the presence of a metal-ligand complex catalyst and a promoter and optionally free ligand to produce said one or more substituted or unsubstituted unsaturated alcohols. The substituted and unsubstituted unsaturated alcohols produced by the processes of this invention can undergo further reaction(s) to afford desired derivatives thereof. This invention also relates in part to reaction mixtures containing one or more substituted or unsubstituted unsaturated alcohols as principal product(s) of reaction.
