3970-62-5Relevant articles and documents
Huston
, p. 1675 (1952)
GAS-TO-LIQUID REACTOR AND METHOD OF USING
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Paragraph 0143; 0144, (2019/08/15)
A device and a process to propagate molecular growth of hydrocarbons, either straight or branched chain structures, that naturally occur in the gas phase to a molecular size sufficient to shift the natural occurring phase to a liquid or solid state is provided. According to one embodiment, the device includes a grounded reactor vessel having a gas inlet, a liquid outlet, and an electrode within the vessel; a power supply coupled to the electrode for creating an elecirostatic field within the vessel for converting the gas to a liquid and or solid state.
Electrochemical alkyl transfer reactions of trialkylborane to carbonyl compounds by use of copper sacrificial anode
Choi, Jung Hoon,Youm, Jong Sung,Cho, Cheon-Gyu,Czae, Myung-Zoon,Hwang, Book Kee,Kim, Jung Sung
, p. 4835 - 4838 (2007/10/03)
Alkyl groups in trialkylboranes were successfully transferred to carbonyl compounds in the presence of the platinum cathode and copper anode by electrochemical method. The new, mild electrochemical alkyl transfer reaction produced various substituted alcohols in good yields.
Gas-phase Unimolecular Chemistry of Ethyl Butyl Ketone Cations
Bouchoux, Guy,Flammang, Robert,Jaudon, Pascale,Lefevre, Odile
, p. 1189 - 1196 (2007/10/02)
Mass spectra of the four isomeric ethyl butyl ketones, C2H5CO-n-C4H9 (1), C2H5CO-iso-C4H9 (2), C2H5CO-sec-C4H9 (3) and C2H5CO-t-C4H9 (4), are reported.The structure of the fragment ions produced from precursors of both high and low internal energy were identified by collision experiments in a six-sector mass-spectrometer.Metastable molecular ions 1(+.) and 2(+.) behave identically in expelling CH3(.), C3H6 and C2H5(.) to produce the same fragment ions: (+), (+.) and a mixture of (+) and (+), respectively.The key isomerization step between 1(+.) and 2(+.) is a 1,2-enol-olefin shift.Metastable molecular ions 3(+.) and 4(+.) give essentially ethene and ethyl losses, respectively; the fragment ions are (+.) and (+).Keto-enol isomerization also occurs to a significant extent for ions 1(+.) and 2(+.) and 3(+.).In contrast, 1,2- or 1,3-ethylhydroxycarbene migrations are only marginal processes.
