39769-24-9

Basic information

• Product Name: 1-(4-methoxystyryl)-4-fluorobenzene
• Synonyms: 1-(4-methoxystyryl)-4-fluorobenzene
• CAS NO: 39769-24-9
• Molecular Weight: 228.266
• Mol File: 39769-24-9.mol
• Article Data: 41

Chemical Properties

• CAS DataBase Reference: 1-(4-methoxystyryl)-4-fluorobenzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(4-methoxystyryl)-4-fluorobenzene(39769-24-9)
• EPA Substance Registry System: 1-(4-methoxystyryl)-4-fluorobenzene(39769-24-9)

Safety Data

• Hazardous Substances Data: 39769-24-9(Hazardous Substances Data)

Upstream product

• 38693-94-6 (E)-4-<2-(4-fluorophenyl)ethenyl>phenol 
• 77-78-1 dimethyl sulfate 
• 405-99-2 para-fluorostyrene 
• 696-62-8 para-iodoanisole 
• 175342-41-3 C₁₂H₁₉O₄P 
• 459-57-4 4-fluorobenzaldehyde 
• 824-94-2 p-methoxybenzyl chloride 
• 459-46-1 4-Fluorobenzyl bromide 
• 352-11-4 1-chloromethyl-4-fluorobenzene 
• 2746-25-0 p-Methoxybenzyl bromide 
• 637-69-4 4-Methoxystyrene 
• 352-13-6 4-flourophenylmagnesium bromide 
• 462-06-6 fluorobenzene 
• 64583-10-4 (Z)-1-fluoro-4-(4-methoxystyryl)benzene 

Downstream Products

• 39769-24-9 (E)-4-fluoro-4'-methoxystilbene 
• 1608492-53-0 (2R,3S,4R,5S)-3,4-bis(4-fluorophenyl)-2,5-bis(4-methoxyphenyl)tetrahydrofuran 
• 38693-94-6 (E)-4-<2-(4-fluorophenyl)ethenyl>phenol 
• 1588534-23-9 C₂₈H₂₀F₂O₂ 
• 24941-76-2 1-fluoro-4-(4-methoxyphenethyl)benzene 

Relevant articles and documents

One-Pot Intermolecular Reductive Cross-Coupling of Deactivated Aldehydes to Unsymmetrically 1,2-Disubstituted Alkenes

The phospha-Peterson reaction between a lithiated secondary phosphane, MesP(Li)TMS, and an aldehyde affords Mes-phosphaalkenes which, upon methanol addition and P-oxidation, react with a second carbonyl compound site specifically to produce unsymmetric alkenes. The E/Z selectivity of the one-pot cross coupling is largely determined by the electronic nature of the aryl substituent of the first aldehyde, with electron-donating groups giving rise to increased amounts of Z-alkenes.

Illuminating Stannylation

We have developed photoboosted stannylation reactions of terminal alkynes (linear-selective hydrostannylation) and fluoroarenes (defluorostannylation), in which the stannyl anion is photoexcited to an excited triplet (T1) stannyl diradical species. This u

An Interrupted Pummerer/Nickel-Catalysed Cross-Coupling Sequence

An interrupted Pummerer/nickel-catalysed cross-coupling strategy has been developed and used in the elaboration of styrenes. The operationally simple method can be carried out as a one-pot process, involves the direct formation of stable alkenyl sulfonium salt intermediates, utilises a commercially available sulfoxide, catalyst, and ligand, operates at ambient temperature, accommodates sp-, sp2-, and sp3-hybridised organozinc coupling partners, and delivers functionalised styrene products in high yields over two steps. An interrupted Pummerer/cyclisation approach has also been used to access carbo- and heterocyclic alkenyl sulfonium salts for cross-coupling.