40141-09-1

Basic information

• Product Name: 3-(4-methoxyphenyl)cyclohexene
• Synonyms: 3-(4-methoxyphenyl)cyclohexene
• CAS NO: 40141-09-1
• Molecular Weight: 188.269
• Mol File: 40141-09-1.mol
• Article Data: 23

Chemical Properties

• CAS DataBase Reference: 3-(4-methoxyphenyl)cyclohexene(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(4-methoxyphenyl)cyclohexene(40141-09-1)
• EPA Substance Registry System: 3-(4-methoxyphenyl)cyclohexene(40141-09-1)

Safety Data

• Hazardous Substances Data: 40141-09-1(Hazardous Substances Data)

Upstream product

• 100-66-3 methoxybenzene 
• 1521-51-3 rac-3-bromocyclohexene 
• 76644-52-5 rac-3-acetoxycyclohexene 
• 623-26-7 terephthalonitrile 
• 20758-60-5 1-(4-methoxyphenyl)cyclohexene 
• 3352-93-0 2-cyclohexenyl benzoate 
• 21130-91-6 triethoxy(4-methoxyphenyl)silane 
• 696-62-8 para-iodoanisole 
• 104-92-7 1-bromo-4-methoxy-benzene 
• 110-83-8 cyclohexene 
• 5720-07-0 4-methoxyphenylboronic acid 
• 1165952-91-9 cyclohexa-1,3-diene 
• 13139-86-1 4-methoxyphenyl magnesium bromide 
• 57981-18-7 N-cyclohex-2-enyl-4-methyl-benzenesulfonamide 

Relevant articles and documents

A Change from Kinetic to Thermodynamic Control Enables trans-Selective Stereochemical Editing of Vicinal Diols

Here, we report the selective, catalytic isomerization of cis-1,2-diols to trans-diequatorial-1,2-diols. The method employs triphenylsilanethiol (Ph3SiSH) as a catalyst and proceeds under mild conditions in the presence of a photoredox catalyst and under

Preparation of Functionalized Diorganomagnesium Reagents in Toluene via Bromine or Iodine/Magnesium-Exchange Reactions

A wide range of polyfunctionalized di(hetero)aryl- and dialkenyl-magnesium reagents are prepared in toluene within 10 to 120 minutes between 78 C and 25 C via an I/Mg- or Br/Mg-exchange reaction using reagents of the general formula R2Mg (R = sBu, Mes). Highly sensitive functional groups, such as triazene or nitro, are tolerated in these exchange reactions, enabling the synthesis of various functionalized (hetero)arene and alkene derivatives after quenching with several electrophiles including allyl bromides, acyl chlorides, aldehydes, ketones, and aryl iodides.

Sulfur-mediated allylic C-H arylation, epoxidation, and aziridination

Transition-metal-free, sulfur-mediated allylic C-H arylation, epoxidation, and aziridination were realized through one-pot procedures. The reaction design involved initial addition between olefins and triflic anhydride activated sulfoxides, followed by subsequent reactions of the allylic sulfur ylides generated under basic conditions with arylboronic acids, aldehydes, or aldimines, to give allylic arylation, epoxidation, or aziridination products, respectively.