40226-15-1Relevant articles and documents
Template-directed syntheses of rigid oligorotaxanes under thermodynamic control
Belowich, Matthew E.,Valente, Cory,Stoddart, J. Fraser
supporting information; experimental part, p. 7208 - 7212 (2010/12/18)
Strategically placing secondary dialkyl-ammonium recognition sites at the magic distance of 3.5 A apart in the dumbbell components of a series of oligorotaxanes (see picture) renders otherwise conformationally floppy [n]rotaxanes rigid and rodlike. These oligorotaxanes form with near-quantitative conversion under thermodynamic control using dynamic covalent chemistry.
Expedient protocol for solid-phase synthesis of secondary and tertiary amines
Olsen, Christian A.,Witt, Matthias,Jaroszewski, Jerzy W.,Franzyk, Henrik
, p. 1935 - 1938 (2007/10/03)
Equation presented. An expedient solid-phase synthetic approach to secondary and tertiary amines was developed. The protocol employs conversion of resin-bound amino alcohols to the corresponding iodides, followed by iodide displacement with primary or sec
