405-06-1Relevant articles and documents
Pd-Catalyzed Etherification of Nitroarenes
Matsushita, Naoki,Kashihara, Myuto,Formica, Michele,Nakao, Yoshiaki
supporting information, p. 2209 - 2214 (2021/07/20)
The Pd-catalyzed etherification of nitroarenes with arenols has been achieved using a new rationally designed ligand. Mechanistic insights were used to design the ligand so that both the oxidative addition and reductive elimination steps of a plausible catalytic cycle were facilitated. The catalytic system established here provides direct access to a range of unsymmetrical diaryl ethers from nitroarenes.
A single phosphine ligand allows palladium-catalyzed intermolecular C-O bond formation with secondary and primary alcohols
Wu, Xiaoxing,Fors, Brett P.,Buchwald, Stephen L.
supporting information; experimental part, p. 9943 - 9947 (2011/12/05)
Forging a bond: An efficient, general palladium catalyst for C-O bond-forming reactions of secondary and primary alcohols with a range of aryl halides has been developed using the ligand 1. Heteroaryl halides, and for the first time, electron-rich aryl halides can be coupled with secondary alcohols. A diverse set of substrate combinations are possible with just a single ligand, thus obviating the need to survey multiple ligands. Copyright
Substituted acid derivatives useful as antidiabetic and antiobesity agents and method
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, (2008/06/13)
Compounds are provided which have the structure wherein Q is C or N, A is 0 or S, Z is O or a bond, X is CH or N and R1, R2, R2a, R2b, R2c, R3, Y, x, m, and n are as defined herein, which compounds are useful as antidiabetic, hypolipidemic, and antiobesity agents.
