41018-52-4

Basic information

• Product Name: (4-bromophenyl)-λ³-iodanediyl diacetate
• Synonyms: (4-bromophenyl)-λ³-iodanediyl diacetate
• CAS NO: 41018-52-4
• Molecular Weight: 400.995
• Mol File: 41018-52-4.mol
• Article Data: 13

Chemical Properties

• CAS DataBase Reference: (4-bromophenyl)-λ³-iodanediyl diacetate(CAS DataBase Reference)
• NIST Chemistry Reference: (4-bromophenyl)-λ³-iodanediyl diacetate(41018-52-4)
• EPA Substance Registry System: (4-bromophenyl)-λ³-iodanediyl diacetate(41018-52-4)

Safety Data

• Hazardous Substances Data: 41018-52-4(Hazardous Substances Data)

Upstream product

• 589-87-7 1,4-bromoiodobenzene 
• 108-24-7 acetic anhydride 
• 127-09-3 sodium acetate 
• 64-19-7 acetic acid 
• 3240-34-4 [bis(acetoxy)iodo]benzene 
• 108-86-1 bromobenzene 

Downstream Products

• 589-87-7 1,4-bromoiodobenzene 
• 64-19-7 acetic acid 
• 490-83-5 L-dehydroascorbic acid 
• 10259-08-2 acetoxy-1 nitroso-1 cyclohexane 
• 1220515-99-0 3-[benzyl(4-bromophenyl)amino]-2-iodocyclohex-2-enone 
• 1220515-88-7 3-[bis(4-bromophenyl)amino]-2-iodocyclohex-2-enone 
• 1382354-98-4 (2-(2-(t-butoxycarbonylamino)ethyl)phenyl)(4-bromophenyl)iodonium p-toluenesulfonate 
• 1382355-08-9 (2-(2-(benzyloxycarbonylamino)ethyl)phenyl)(4-bromophenyl)iodonium p-toluenesulfonate 
• 1382355-18-1 (2-(2-acetamidoethyl)phenyl)(4-bromophenyl)iodonium p-toluenesulfonate 
• 1382355-28-3 (2-(2-(3,3-diethylureido)ethyl)phenyl)(4-bromophenyl)iodonium p-toluenesulfonate 
• 73178-08-2 1-[hydroxy(tosyloxy)iodo]-4-bromobenzene 
• 1401229-20-6 1-(2-(4-bromophenyl)-1-phenylethoxy)-2,2,6,6-tetramethylpiperidine 
• 139139-81-4 bis(4-bromophenyl)iodonium triflate 

Relevant articles and documents

Preparation and Synthetic Applicability of Imidazole-Containing Cyclic Iodonium Salts

A novel approach to the preparation of imidazole-substituted cyclic iodonium salts has been developed via the oxidative cyclization of 1-phenyl-5-iodoimidazole using a cheap and available Oxone/H2SO4 oxidative system. The structure of the new polycyclic heteroarenes has been confirmed by single-crystal X-ray diffractometry, revealing the characteristic structure features for cyclic iodonium salts. The newly produced imidazole-flanked cyclic iodonium compounds were found to readily engage in a heterocyclization reaction with elemental sulfur, affording benzo[5,1-b]imidazothiazoles in good yields.

Safer Synthesis of (Diacetoxyiodo)arenes Using Sodium Hypochlorite Pentahydrate

A practical method for the preparation of (diacetoxyiodo)arene ArI(OAc)2 is described. The use of commercially available sodium hypochlorite pentahydrate (NaClO·5H2O) enabled safe, rapid, and inexpensive oxidation of iodoarenes with electron-withdrawing and -donating substituents. The method allows tandem divergent access to synthetically useful organo-λ3-iodanes such as hydroxyl(tosyloxy)iodobenzene, iodosylbenzene, iodonium ylide, etc.

Metathetical redox reaction of (diacetoxyiodo)arenes and iodoarenes

The oxidation of iodoarenes is central to the field of hypervalent iodine chemistry. It was found that the metathetical redox reaction between (diacetoxyiodo)arenes and iodoarenes is possible in the presence of a catalytic amount of Lewis acid. This discovery opens a new strategy to access (diacetoxyiodo)arenes. A computational study is provided to rationalize the results observed.