4165-86-0

Basic information

• Product Name: [(1E)-1-ethylprop-1-en-1-yl]benzene
• CAS NO: 4165-86-0
• Molecular Formula: C₁₁H₁₄
• Molecular Weight: 146.2289
• Mol File: 4165-86-0.mol
• Article Data: 10

Chemical Properties

• Boiling Point: 204°C at 760 mmHg
• Flash Point: 69.7°C
• Density: 0.876g/cm³
• Vapor Pressure: 0.385mmHg at 25°C
• Refractive Index: 1.512
• CAS DataBase Reference: [(1E)-1-ethylprop-1-en-1-yl]benzene(CAS DataBase Reference)
• NIST Chemistry Reference: [(1E)-1-ethylprop-1-en-1-yl]benzene(4165-86-0)
• EPA Substance Registry System: [(1E)-1-ethylprop-1-en-1-yl]benzene(4165-86-0)

Safety Data

• Hazardous Substances Data: 4165-86-0(Hazardous Substances Data)

Upstream product

• 93-58-3 benzoic acid methyl ester 
• 1754-88-7 ethylenetriphenylphosphorane 
• 108-98-5 thiophenol 
• 4706-43-8 1-benzyl-1H-benzotriazole 
• 1565-71-5 3-phenylpentan-3-ol 
• 100-58-3 phenylmagnesium bromide 
• 96-22-0 pentan-3-one 
• 100-59-4 phenylmagnesium chloride 
• 87437-00-1 3-diphenoxyphosphoryloxypent-2-ene 
• 1530-32-1 ethyltriphenylphosphonium bromide 
• 93-55-0 1-phenyl-propan-1-one 
• 1528-39-8 3-phenyl-2-pentanone 
• 108-86-1 bromobenzene 
• 873-66-5 1-propenylbenzene 

Downstream Products

• 869368-16-1 4-tert-butyl-2-(3-phenylpent-3-yl)phenol 
• 4564-82-3 threo-3-phenylpentan-2-ol 
• 74365-66-5 (2S,3R)-(-)-threo-3-phenyl-2-pentanol 
• 869368-17-2 5-tert-butyl-2-hydroxy-3-(3-phenylpent-3-yl)benzaldehyde 
• 93-55-0 1-phenyl-propan-1-one 
• 4564-82-3 (2R,3S)-3-phenyl-2-pentanol 
• 1196-00-5 d,l-Isopinocamphenol 

Relevant articles and documents

Triphosgene and DMAP as Mild Reagents for Chemoselective Dehydration of Tertiary Alcohols

The utility of triphosgene and DMAP as mild reagents for chemoselective dehydration of tertiary alcohols is reported. Performed in dichloromethane at room temperature, this reaction is readily tolerated by a broad scope of substrates, yielding alkenes preferentially with the (E)-geometry. While formation of the Hofmann products is generally favored, a dramatic change in alkene selectivity toward the Zaitzev products is observed when the reaction is carried out in dichloroethane at reflux.

Enantioselective Oxidative Rearrangements with Chiral Hypervalent Iodine Reagents

A stereoselective hypervalent iodine-promoted oxidative rearrangement of 1,1-disubstituted alkenes has been developed. This practically simple protocol provides access to enantioenriched α-arylated ketones without the use of transition metals from readily

A sterically modified (salen)chromium(III) complex - An efficient catalyst for high-pressure asymmetric allylation of aldehydes

A novel (salen)chromium(III) catalyst with a modified salen ligand was synthesised in a simple way starting from readily available precursors. High-pressure allylation reaction of aromatic and aliphatic aldehydes with allyltributyltin upon application of