417698-17-0

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 108-95-2 phenol 
• 17614-10-7 phenyl N-isopropylcarbamate 

Downstream Products

• 15288-53-6 o-(trimethylsilyl)phenol 
• 444095-29-8 2-hydroxy-3-(trimethylsilyl)benzaldehyde 
• 2040-86-0 2-bromo-6-iodophenol 
• 899427-35-1 2-(tert-butyldimethylsilyloxy)phenylmethyl-6-(trimethylsilyl)phenyl isopropylcarbamate 
• 899427-37-3 2-(tert-butyldimethylsilyloxy)phenylmethyl-6-iodophenyl isopropylcarbamate 
• 899427-34-0 acetic acid (2-isopropylcarbamoyloxy-3-trimethylsilanyl-phenyl)-phenyl-methyl ester 
• 899427-31-7 2-hydroxyphenylmethyl-6-(trimethylsilyl)phenyl isopropylcarbamate 
• 899427-30-6 2-benzoyl-6-(trimethylsilyl)phenyl isopropylcarbamate 
• 899427-36-2 acetic acid (3-iodo-2-isopropylcarbamoyloxy-phenyl)-phenyl-methyl ester 
• 899427-33-9 2-benzoyl-6-iodophenyl isopropylcarbamate 
• 899427-38-4 2-hydroxyphenylmethyl-6-iodophenyl isopropylcarbamate 
• 899427-29-3 2-bromo-6-(trimethylsilyl)phenyl isopropylcarbamate 
• 899427-32-8 2-bromo-6-iodophenyl isopropylcarbamate 

Relevant academic research and scientific papers

Efficient synthesis of 2-(trimethylsilyl)phenyl trifluoromethanesulfonate: A versatile precursor to o-benzyne

(Chemical Equation Presented) An efficient procedure for the gram-scale preparation of 2-(trimethylsilyl)phenyl trifluoromethanesulfonate, a versatile precursor to o-benzyne, is presented. The three-step sequence utilizes phenol as the starting material, requires only one chromatographic purification, and ultimately delivers the desired silyltriflate in 66% overall yield. 2009 American Chemical Society.

Synthesis of substituted phenols by directed ortho-lithiation of in situ N-silyl-protected O-aryl N-monoalkylcarbamates

A simple, high-yield procedure has been developed for the ortho-lithiation and subsequent ortho-substitution of phenols by a manifold of electrophiles. N,C-Dilithiation of O-aryl N-monoalkylcarbamates proved to be impossible due to a cleavage reaction of