41931-18-4

Basic information

• Product Name: 4-BROMOPHENYLHYDRAZINE HYDROCHLORIDE
• Synonyms: (4-bromophenyl)-hydrazinmonohydrochloride;1-(p-bromophenyl)-hydrazinhydrochloride;P-BROMOPHENYLHYDRAZINE HYDROCHLORIDE;P-BROMOPHENYLHYDRAZINIUM CHLORIDE;4-BROMOPHENYLHYDRAZINE HCL;4-BROMOPHENYLHYDRAZINE MONOHYDROCHLORIDE;4-BROMOPHENYLHYDRAZINIUM CHLORIDE;LABOTEST-BB LT01143342
• CAS NO: 41931-18-4
• Molecular Formula: C6H8BrClN2
• Molecular Weight: 223.5
• EINECS: 255-590-4
• Product Categories: Aromatic Hydrazides, Hydrazines, Hydrazones and Oximes
• Mol File: 41931-18-4.mol
• Article Data: 38

Chemical Properties

• Melting Point: 220-230 °C (dec.)(lit.)
• Boiling Point: 285.6°C at 760 mmHg
• Flash Point: 126.5°C
• Appearance: /
• Vapor Pressure: 0.00278mmHg at 25°C
• Storage Temp.: Keep in dark place,Inert atmosphere,Room temperature
• CAS DataBase Reference: 4-BROMOPHENYLHYDRAZINE HYDROCHLORIDE(CAS DataBase Reference)
• NIST Chemistry Reference: 4-BROMOPHENYLHYDRAZINE HYDROCHLORIDE(41931-18-4)
• EPA Substance Registry System: 4-BROMOPHENYLHYDRAZINE HYDROCHLORIDE(41931-18-4)

Safety Data

• Hazard Codes: C,Xi
• Statements: 34
• Safety Statements: 26-36/37/39-45
• RIDADR: UN 3261 8/PG 2
• WGK Germany: 3
• RTECS: MV0800000
• Hazardous Substances Data: 41931-18-4(Hazardous Substances Data)

Usage

General Description

4-Bromophenylhydrazine hydrochloride is a chemical compound that consists of a hydrazine derivative with a 4-bromophenyl group. It is commonly used as a reagent in the synthesis of pharmaceuticals and agrochemicals. 4-BROMOPHENYLHYDRAZINE HYDROCHLORIDE is also a potent and selective inhibitor of the enzyme monoamine oxidase (MAO), which plays a role in the metabolism of neurotransmitters in the brain. It is important to handle 4-Bromophenylhydrazine hydrochloride with caution, as it is considered hazardous and can cause irritation to the skin and respiratory system upon contact or inhalation.

InChI:InChI=1/C6H7BrN2.ClH/c7-5-1-3-6(9-8)4-2-5;/h1-4,9H,8H2;1H

Upstream product

• 2028-85-5 (4-bromophenyl)diazonium chloride 
• 106-37-6 1.4-dibromobenzene 
• 106-40-1 4-bromo-aniline 
• 1352877-20-3 (3R,4S)-4-hydroxy-2-oxotetrahydrofuran-3-yl 2-(2-(4-bromophenyl)hydrazinyl)-2-oxoethanoate 
• 100-63-0 phenylhydrazine 

Downstream Products

• 128102-54-5 phenyl-(5-phenyl-[1,2,4]oxadiazol-3-yl)-methanone (4-bromo-phenyl)-hydrazone 
• 80815-90-3 N-(4-Bromo-phenyl)-N'-[1-phenyl-1-(5-phenyl-[1,2,4]oxadiazol-3-yl)-meth-(Z)-ylidene]-hydrazine 
• 14687-14-0 3-O-Benzyl-D-erythrose-(p-bromphenyl)-osazon 
• 72016-68-3 5-bromo-2-methyl-1H-indole-3-acetic acid ethyl ester 
• 24885-35-6 N-[2-(5-bromo-1H-indol-3-yl)ethyl]benzamide 
• 21064-34-6 8-bromo-11H-benzo[a] carbazole 
• 80776-69-8 6-[(4-Bromo-phenyl)-hydrazono]-6,7,8,9-tetrahydro-pyrido[2,1-b]quinazolin-11-one 
• 80776-69-8 6-[(4-Bromo-phenyl)-hydrazono]-6,7,8,9-tetrahydro-11H-pyrido[2,1-b]quinazoline-11-one 
• 71987-66-1 2-(5-bromo-2-methyl-1H-indol-3-yl)acetic acid 
• 1429924-49-1 5-((2-(4-bromophenyl)hydrazono)methyl)-4,6-dichloropyrimidine 
• 832715-52-3 4-chloro-1-(4-bromophenyl)-1H-pyrazolo[3,4-d]pyrimidine 
• 1448308-30-2 3-{1-[(E)-2-(4-bromophenyl)hydrazono]ethyl}-2H-chromen-2-one 
• 15754-94-6 4-bromo-1-(4-bromophenyl)pyrazole 
• 1259224-11-7 5-bromo-2,3-diphenyl-1H-indole 

Relevant articles and documents

Rhodium(III)-catalyzed in situ oxidizing directing group- assisted c-h bond activation and olefination: A route to 2-vinylanilines

A new and efficient method for the synthesis of 2-vinylanilines from the reaction of arylhydrazine hydrochlorides with alkenes and diethyl ketone via a rhodium-catalyzed C-H activation is described. The oxidant-free olefination reaction involves the in situ generation of an -N-N=CR1R2 moiety as the oxidizing directing group thus providing an easy access to 2-vinylanilines.

Highly Efficient Synthesis of Hindered 3-Azoindoles via Metal-Free C-H Functionalization of Indoles

Although 3-azoindoles have recently emerged as an appealing family of photoswitch molecules, the synthesis of such compounds has been poorly covered in the literature. Herein a high-yielding and operationally simple protocol is reported allowing the synthesis of 3-azoindoles, featuring important steric hindrance around the azo motif. Remarkably, this C-H coupling is characterized by excellent atom economy and occurs under metal-free conditions, at room temperature, and within few minutes, delivering the expected products in excellent yields (quantitatively in most of the cases). Accordingly, a library of new molecules, with potential applications as photochromic compounds, is prepared.

An electroluminescen compound and an electroluminescent device comprising the same

The present invention relates to an organic light-emitting compound represented by chemical formula 1. An organic electroluminescent device comprising the organic light-emitting compound in the present invention has excellent power efficiency, light-emitting efficiency, and long life cycle because the present invention can be operated by a lower driving-voltage in comparison with a device comprising conventional phosphorescent host materials.