4353-06-4

Basic information

• Product Name: 2-N-NONYL-1,3-DIOXOLANE
• Synonyms: RARECHEM AL BP 0168;2-N-NONYL-1,3-DIOXOLANE;2-nonyl-3-dioxolane;2-nonyl-1,3-dioxolane;2-Nonyldioxolane
• CAS NO: 4353-06-4
• Molecular Formula: C₁₂H₂₄O₂
• Molecular Weight: 200.32
• EINECS: 224-422-1
• Mol File: 4353-06-4.mol
• Article Data: 7

Chemical Properties

• Boiling Point: 247.7 °C at 760 mmHg
• Flash Point: 95.9 °C
• Appearance: /
• Density: 0.894 g/cm³
• Vapor Pressure: 0.0397mmHg at 25°C
• Refractive Index: 1.438
• CAS DataBase Reference: 2-N-NONYL-1,3-DIOXOLANE(CAS DataBase Reference)
• NIST Chemistry Reference: 2-N-NONYL-1,3-DIOXOLANE(4353-06-4)
• EPA Substance Registry System: 2-N-NONYL-1,3-DIOXOLANE(4353-06-4)

Safety Data

• Hazardous Substances Data: 4353-06-4(Hazardous Substances Data)

Usage

General Description

2-N-Nonyl-1,3-dioxolane is a chemical compound with the molecular formula C12H24O2. It is a nonyl-substituted dioxolane compound, consisting of a six-membered dioxolane ring with a nonyl side chain attached. 2-N-NONYL-1,3-DIOXOLANE is commonly used as a solvent in various industrial and commercial applications, including in the manufacturing of adhesives and sealants, as well as in the formulation of cleaning and degreasing products. It is known for its high solvency power and low volatility, making it a suitable choice for applications that require effective cleaning and degreasing capabilities without excessive evaporation. Additionally, 2-N-Nonyl-1,3-dioxolane is also used as a chemical intermediate in the synthesis of other organic compounds. However, it is important to handle this chemical with care, as it may present certain health and safety hazards if not used properly.

InChI:InChI=1/C12H24O2/c1-2-3-4-5-6-7-8-9-12-13-10-11-14-12/h12H,2-11H2,1H3

Upstream product

• 102237-05-8 2-(5-[2]thienylmethyl-[2]thienyl)-[1,3]dioxolane 
• 112-31-2 caprinaldehyde 
• 7381-30-8 2,2,7,7-tetramethyl-3,6-dioxa-2,7-disilaoctane 
• 936-51-6 2-phenyl-1,3-dioxolane 
• 7779-41-1 1,1-dimethoxy decane 
• 35250-77-2 5-(2-thienylmethyl)-thiophene-2-carbaldehyde 
• 107-21-1 ethylene glycol 
• 4353-07-5 2-non-8-ynyl-[1,3]dioxolane 
• 109734-34-1 N-methyl-dec-9-ynanilide 
• 1642-49-5 dec-9-ynoic acid 
• 100131-19-9 9-decynoic acid chloride 
• 103273-20-7 dec-9-yn-al 
• 34764-02-8 decanal diethyl acetal 

Downstream Products

• 112-31-2 caprinaldehyde 
• 334-48-5 1-decanoic acid 
• 1122103-40-5 C₁₇H₃₂O₃ 
• 16179-41-2 2-hydroxyethyl decanoate 
• 2311-59-3 isopropyl decanoate 
• 110-38-3 decanoic acid ethyl ester 
• 110-42-9 Methyl decanoate 

Relevant articles and documents

Synthesis and Hydrolysis of Chemodegradable Cationic Surfactants Containing the 1,3-Dioxolane Moiety

In acid-catalyzed reactions of long-chain aliphatic aldehydes (Ia-d where a = n-C7H15; b = n-C9H19; c = n-C11H23; d = n-C13H27), and tridecan-7-on (Ie) with 3-chloro-1,2-propane-diol, 2-alkyl- and 2,2-dihexyl-4-chloromethyl-1,3-dioxolanes (IIa-e) were obtained.They were reacted with anhydrous dimethylamine to obtain, respectively, 2-alkyl- and dimethylamines (IIIa-e), which were quaternized with methyl bromide to obtain the desired ammonium bromides (IVa-e).The structure and purity of the compounds was proved by mass spectrometry and proton magnetic resonance spectroscopy.Additionally, trimethylammonium bromide and trimethylammonium bromide were synthesized as nonaggregating standards.Hydrolysis reactions of the synthesized ammonium bromides were performed by 0.1 M hydrochloric acid in 1:1 (vol/vol) 1,4-dioxane-water mixtures at 50, 60 and 70 deg C.Rate constants of hydrolysis reactions were determined by observing carbonyl group formation at 280 nm.The hydrolytic reactivity of the studied surfactants (IVa-c,e) was determined under unaggregated conditions.Compound IVd showed decreased reactivity.The length of the 2-alkyl group has a minor effect on rate constant values.The influence of various substituents at the C-4 atom of the 2-nonyl-1,3-dioxolan-4-yl derivatives on rate constants was also investigated. KKEY WORDS: trimethylammonium bromides, trimethylammonium bromide, chemodegradable acetal-type cationic surfactants, kinetic and thermodynamic parameters of 1,3-dioxolane ring hydrolysis.

Acetalization of aldehydes and ketones over H4[SiW 12O40] and H4[SiW12O 40]/SiO2

H4[SiW12O40] (H-SiW12) is demonstrated to be able to efficiently catalyze the acetalization of aldehydes and ketones with ethylene glycol and 1,3-propanediol. Nevertheless, the possible leaching and the recycling of H-SiW12 are two major disadvantages that largely restrict its further application in industry. Moreover, H 4[SiW12O40] tends to deactivate strong proton sites due to the small surface area of 10 m2 g-1. Due to interactions with surface silanol groups, the proton sites of polyoxometalates (POMs) on SiO2 are less susceptible to deactivation. As such, immobilization of H4[SiW12O40] onto SiO 2 leads to the heterogeneous catalyst H4[SiW 12O40]/SiO2 (H-SiW12/SiO 2), which can catalyze the acetalization of aldehydes and ketones with ethylene glycol and 1,3-propanediol selectively and efficiently without the need of a drying agent. The acetalization process can proceed smoothly at a relatively low temperature under solvent-free conditions. The catalyst of H 4[SiW12O40]/SiO2 can be recycled at least ten times without an obvious decrease in its catalytic activity. As far as we know, the TONs of the H-SiW12/SiO2-catalyzed acetalization of cyclohexanone with ethylene glycol, and benzaldehyde with 1,3-propanediol are the highest reported so far.

A remarkable iodine-catalyzed protection of carbonyl compounds

We report here a remarkably simple molecular iodine-catalyzed protection method for various carbonyl compounds as ketals in a general reaction. The iodine-catalyzed reaction of mandelic acid and lactic acid with several aldehydes has furnished a highly diastereoselective synthesis of cis and trans dioxolanones.