4439-20-7Relevant articles and documents
Potentiometric and AM1d studies of the equilibria between silver(I) and diaza-15-crown and diaza-18-crown ethers with nitrogen in different positions in various solvents
Kira, Jaromir,Niedzialkowski, Pawel,Ossowski, Tadeusz
, p. 180 - 190 (2013)
Complex formation and stability constants between typical and atypical diaza-15-crown and diaza-18-crown ethers with silver(I) were determined in methanol, acetonitrile and propylene carbonate by the potentiometric method. In two of the diaza crown ethers, AA-diaza-15 and AA-diaza-18-crown, two nitrogens in the macrocyclic ring replaced two consecutive oxygens instead of two opposite ones in the two other diaza crown ethers. It was found that complexes of 1:1 and 1:2 metal-to-ligand stoichiometry were formed. The solvent composition and cavity size of crown ethers significantly influences the stability constants of complexes. AA-diaza-15 and AA-diaza-18-crown ethers were examined for comparison with diaza-15-crown and diaza-18-crown ethers. AA-diaza crown ethers formed less stable 1:1 metal-to-ligand complexes with silver(I) than typical diaza crown ethers but their ability to form 1:2 metal-to-ligand complexes was stronger. The energetically most favorable structures of the 1:1 metal-to-ligand complexes were calculated and visualized by the AM1d method at the semiempirical level of theory.
PROCESS FOR PREPARING EDFA AND/OR EDMFA AND DETA AND/OR TETA
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Paragraph 0486; 0489, (2013/03/26)
A process for reacting ethylenediamine (EDA) with formaldehyde to give ethylenediamine-formaldehyde adduct (EDFA) and/or ethylenediamine-monoformaldehyde adduct (EDMFA), which comprises performing the reaction of FA with EDA at a temperature in the range from 20 to 70° C.
Ceramide-like compounds and a method for preparation thereof, and a cosmetic composition containing the same
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, (2008/06/13)
Disclosed herein is a ceramide-like compound having properties of the natural ceramides, and a method for producing the same, and a cosmetic composition containing the same as a active ingredient.