4464-23-7Relevant academic research and scientific papers
Thermal decomposition of cadmium formate in inert and oxidative atmosphere
Ma?ecka, Barbara,?acz, Agnieszka
, p. 12 - 16 (2008)
Thermal decomposition of cadmium formate, Cd(HCOO)2, was studied in dynamic helium and air atmosphere by means of simultaneous TGA, DTA and MS analysis. It was found that the cadmium formate decomposes at about 210 °C to metallic cadmium and cadmium carbonate which next decomposes with formation of cadmium oxide. In helium cadmium melts, evaporates and the reaction residue consists of CdO and a small amount of elementary carbon formed in result of pyrolysis of formate groups. In air cadmium oxidizes and the final solid product of decomposition is CdO. The gaseous products of cadmium formate decomposition are: carbon dioxide, water, carbon monoxide, formaldehyde, methyl alcohol and methyl formate.
Interaction of Cd and Zn with biologically important ligands characterized using solid-state NMR and ab initio calculations
Kidambi, Srikanth S.,Lee, Dong-Kuk,Ramamoorthy
, p. 3142 - 3151 (2003)
For the first time, coordination geometry and structure of metal binding sites in biologically relevant systems are studied using chemical shift parameters obtained from solid-state NMR experiments and quantum chemical calculations. It is also the first e
Further investigations on the thermo-physical characteristics of cadmium formate single crystals
Sekkina, M.M.Abou,Morsi,El-Geassy
, p. 1 - 7 (1985)
The dehydration mechanism of cadmium(II) formate dihydrate was investigated using X-ray diffraction, infrared absorption, thermogravimetric analysis and differential thermal analysis. The results obtained showed a stepwise water loss mechanism accompanied by strong endothermic peaks. A mechanism was proposed to explain the dehydration reaction.
Shape control of zincblende CdSe nanoplatelets
Bertrand, Guillaume H.V.,Polovitsyn, Anatolii,Christodoulou, Sotirios,Khan, Ali Hossain,Moreels, Iwan
supporting information, p. 11975 - 11978 (2016/10/09)
The lateral dimensions of CdSe nanoplatelets have a strong and unique influence on their opto-electronic properties, with sizes that can be tuned from the weak to the strong exciton confinement regime. There are state-of-the-art reports on several nanoplatelet syntheses; however, at present only the thickness is well-controlled. We demonstrate here that we can achieve a control over the aspect ratio and overall nanoplate area by carefully adjusting the reagents that induce the in-plane growth. A variation of the fraction of hydrated Cd(OAc)2 in a Cd(OAc)2/Cd(OAc)2·2H2O mixture tailors the nanoplatelet aspect ratio. This occurs independently of the reaction time, which can be used to fine-tune the overall length and width. An interpretation is given by the in situ formation of a small amount of hydroxide anions that alter the surface energy of specific planes.
Synthesis and characterization of new metal(II) complexes with formates and some nitrogen donor ligands
Czakis-Sulikowska,Czylkowska,Radwanska-Doczekalska,Grodzki,Wojciechowska
, p. 557 - 564 (2008/10/09)
New mixed-ligands complexes with empirical formulae: M(2,4'-bpy) 2L2?H2O (M(II)Zn, Cd), Zn(2-bpy) 3L2?4H2O, Cd(2-bpy)2L 2?3H2O, M(phen)L2?2H
The Cd(HCOO)2-Sr(HCOO)2-H2O system at 25 and 50°C
Vassileva, Violeta Z.
, p. 135 - 139 (2008/10/09)
The solubility in the Cd(HCOO)2-Sr(HCOO)2-H2O system has been studied by the method of physico-chemical analysis at 25 and 50°C. It has been established that only simple salts crystallize in the system at 25°C. A congruent double salt with composition CdSr(HCOO)4.H2O is formed in the system at 50°C. The thermal dehydration and decomposition of the new compound have been investigated by TG, DTA and DSC. The enthalpy of dehydration of CdSr(HCOO)4.H2O has been determined.
