4537-14-8Relevant academic research and scientific papers
Process for the production of phenylalkanes using a hydrocarbon fraction that is obtained from the Fischer-Tropsch process
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Page/Page column 4, (2008/06/13)
A process for the production of phenylalkanes comprising a reaction for alkylation of at least one aromatic compound by at least one hydrocarbon fraction that is directly obtained from the Fischer-Tropsch process comprising linear olefins that have 9 to 16 carbon atoms per molecule and oxygenated compounds is described. Said alkylation reaction is carried out in a catalytic reactor that contains at least one reaction zone that comprises at least one acidic solid catalyst, and said hydrocarbon fraction does not undergo any purification treatment prior to its introduction into said reaction zone.
Nickel(II)-catalyzed dialkylation of aromatic aldehydes with organozinc reagents
Hu, Yulai,Wang, Jin-Xian,Li, Wenbo
, p. 174 - 175 (2007/10/03)
A novel reaction of the dialkylation of arylaldehydes is provided. The reaction of substituted aromatic aldehyde with organozinc halides in the presence of catalytic amount of Ni(acac)2 and a tertiary amine using a silylating agent to give 1-alkyl-1-arylalkanes in satisfactory yields.
Synthesis of Trialkylacetic Acids by the Anodic Oxidation of 3,3-Disubstituted-2-oxo Carboxylic Acids
Rabjohn, Norman,Cranor, W. L.,Schofield, C. M.
, p. 1732 - 1736 (2007/10/02)
The "non-Kolbe" electrolysis of 3,3-disubstituted-2-oxocarboxylates 1-3 in methanol produced mixtures of methyl trialkylacetates 5, trialkylacetaldehydes 6, in some cases 2-hydroxy-3,3,3-trialkylpropionic acids 7, trialkylethylenes 8, and methyl trialkylmethyl ethers 9.When one of the substituents on the 3-carbon of the 2-oxo carboxylate was phenyl 4, molecular rearrangement was not observed.In addition to products 5-9, with the exception of 7, there was obtained with 4 an alkyl phenyl ketone 10.The methyl trisubstituted acetates were saponified to the desired trialkylacetic acids.
