4542-61-4Relevant academic research and scientific papers
Preparation of energetic poly(azolyl)borates as new environmentally benign green-light-emitting species for pyrotechnics
Klapoetke, Thomas M.,Rusan, Magdalena,Sproll, Veronique
, p. 2433 - 2443 (2013/11/19)
Three different energetic poly(azolyl)borates, potassium dihydridobis(4-nitroimidazolyl)borate, sodium dihydridobis(4, 5-dinitroimidazolyl)borate, and sodium dihydridobis(3, 4,5-trinitropyrazolyl) borate, were synthesized as starting materials for metal-f
Partial reduction of trimethoxyborane: An old reaction in a new reactor
Jeffers, Peter M.,Bauer
, p. 1698 - 1701 (2008/10/08)
Forty-fifty percent conversion of trimethoxyborane to HB(OCH3)2 was achieved by passing B(OCH3)3/H2 mixtures through a carefully controlled microwave discharge; almost all of the unconverted reactants were recovered. Similar but much less efficient reductions were obtained by exposing the reactants to focused pulses of CO2 laser radiation [P(26)-P(34) lines of the 9.6-μm band]. We were not successful in reducing trimethoxyborane by activating these mixtures with electrical discharges, with continuous, unfocused laser radiation, or via Hg-photosensitized photolysis. No significant reductions were achieved by any mode of excitation when H2S, NH3, C2H2, or CH4 replaced the H2. However, the reaction B(OCH3)3 + SiH4 = HB(OCH3)2 + SiH3(OCH3) proceeds smoothly under CW laser irradiation.
