4551-62-6Relevant articles and documents
Abstraction of deuterium from dideuteroglycine by aryl radical: A model for 1,4-benzene diradical reactions with proteins
Braslau, Rebecca,Anderson, Marc O.
, p. 4227 - 4230 (1998)
Aryl radicals are generated by oxidation of aryl hydrazine with PbO2 or via photolysis of aryl iodide. Abstraction of deuterium from dideuteroglycine derivatives is demonstrated as a model for the possible reaction of 1,4-aryl diradicals with a
Water Compatible Hypophosphites- d2 Reagents: Deuteration Reaction via Deutero-deiodination in Aqueous Solution
Fang, Jing,Li, Ting,Meng, Lingkui,Song, Zejin,Wan, Qian,Zeng, Jing,Zhao, Xiang
supporting information, (2020/03/13)
Contrary to conventional deuteration approaches which typically entail deuterated solvents and/or moisture exclusion, an unprecedented deutero-deiodination reaction attainable in aqueous (H2O) solution is presented herein. By utilizing the stability of inorganic deuterated calcium/sodium hypophosphites against wayward H/D isotopic exchange within pH 2.5-11.7, these shelf-stable, nontoxic, cost-effective, and environmentally benign deuteration reagents mediate deuteration of a broad range alkyl and aryl iodides with ample isotopic incorporation in aqueous (H2O) solution.
Continuous-flow catalytic deuterodehalogenation carried out in propylene carbonate
Orsy, Gy?rgy,Fül?p, Ferenc,Mándity, István M.
supporting information, p. 956 - 961 (2019/03/11)
A selective continuous-flow (CF) deuterodehalogenation approach is described performed in propylene carbonate, which is considered as one of the greenest solvents. Various CF technologies are known for hydrodehalogenation reactions; however, they are not
