4560-87-6

Upstream product

• 50-00-0 formaldehyd 
• 143-33-9 sodium cyanide 
• 107-14-2 chloroacetonitrile 
• 110-90-7 hexahydro-1,3,5-triazine 
• 542-76-7 3-Chloropropionitrile 

Downstream Products

• 55739-34-9 N-(2-hydroxy-5-methyl-benzyl)-glycine 
• 99984-59-5 4-methoxy-α-methylenamino-cinnamonitrile 
• 104509-48-0 3,4-dimethoxy-α-methylenamino-cinnamonitrile 
• 80-68-2 DL-threonine 
• 109-82-0 methyleneaminoacetonitrile 
• 593-75-9 methyl isocyanate 
• 59264-17-4 N-(methylimino)acetonitrile 
• 628-87-5 iminodiacetonitrile 
• 1071-83-6 N-(phosphonemethyl)glycine 
• 65007-28-5 O,O-diphenyl N-phosphonomethylglycinonitrile 
• 66076-06-0 N,N'-methylenebis-(O,O-diphenyl N-phosphonomethylglycinonitrile) 
• 66075-63-6 O,O-di(p-chlorophenyl) N-phosphonomethylglycinonitrile 
• 66075-69-2 O,O-di(p-methoxyphenyl) N-phosphonomethylglycinonitrile 
• 66075-64-7 O,O-di(3,4-dimethylphenyl) N-phosphonomethylglycinonitrile 

Relevant academic research and scientific papers

Electrolyte and electrochemical device

This application provides an electrolyte and an electrochemical device, wherein the electrolyte comprises an additive A and an additive B, the additive A is present in an amount of 0.001% to 10% by mass in the electrolyte, and the additive B is present in an amount of 0.1% to 10% by mass in the electrolyte. This application can improve the cycle performance and storage performance of the electrochemical device, especially the cycle performance and storage performance of the electrochemical device under high temperature and high voltage conditions.

LITHIUM-ION BATTERY AND APPARATUS

This application provides a lithium-ion battery and an apparatus. The lithium-ion battery includes an electrode assembly and an electrolyte. The electrode assembly includes a positive electrode plate, a negative electrode plate, and a separator. A positive active material of the positive electrode plate includes Lix1Coy1M1-y1O2-z1Qz1, where 0.5≤x1≤1.2, 0.8≤y1≤1.0, 0≤z1≤0.1, M is selected from one or more of Al, Ti, Zr, Y, and Mg, and Q is selected from one or more of F, Cl, and S. The electrolyte contains an additive A, an additive B, and an additive C. The additive A is a polynitrile six-membered nitrogen-heterocyclic compound with a relatively low oxidation potential. The additive B is a silyl phosphite compound or a silyl phosphate compound or a mixture thereof. The additive C is a halogen substituted cyclic carbonate compound.

Lithium-ion battery and apparatus

This application provides a lithium-ion battery and an apparatus. The lithium-ion battery includes an electrode assembly and an electrolyte. The electrode assembly includes a positive electrode plate, a negative electrode plate, and a separator. A positive active material of the positive electrode plate includes Lix1Coy1M1-y1O2-z1Qz1, where 0.5≤x1≤1.2, 0.8≤y11.0, 0≤z1≤0.1, M is selected from one or more of Al, Ti, Zr, Y, and Mg, and Q is selected from one or more of F, Cl, and S. The electrolyte contains an additive A, an additive B, and an additive C. The additive A is a polynitrile six-membered nitrogen-heterocyclic compound with a relatively low oxidation potential. The additive B is an anhydride compound. The additive C is a halogen substituted cyclic carbonate compound.

LITHIUM-ION BATTERY AND APPARATUS

This application provides a lithium-ion battery and an apparatus. The lithium-ion battery includes an electrode assembly and an electrolyte. The electrode assembly includes a positive electrode plate, a negative electrode plate, and a separator. A positive active material of the positive electrode plate includes Lix1Coy1M1-y1O2-z1Qz1, where 0.5≤x1≤1.2, 0.8≤y1≤1.0, 0≤z1≤0.1, M is selected from one or more of Al, Ti, Zr, Y, and Mg, and Q is selected from one or more of F, Cl, and S. The electrolyte contains an additive A that is a polynitrile six-membered nitrogen-heterocyclic compound with a relatively low oxidation potential. The lithium-ion battery has superb cycle performance and storage performance, especially under high-temperature and high-voltage conditions.

LITHIUM-ION BATTERY AND APPARATUS

The present application provides a lithium-ion battery and an apparatus, and the lithium-ion battery includes an electrode assembly and an electrolytic solution, the electrode assembly includes a positive electrode sheet, a negative electrode sheet and a separation film. A positive active material of the positive electrode sheet includes Lix1Coy1M1-yO2-z1Qz1, 0.5≤x1≤1.2, 0.8≤y1≤1.0, 0≤z1≤0.1, M is selected from one or more of Al, Ti, Zr, Y, and Mg, and Q is selected from one or more of F, Cl, and S. The electrolytic solution contains vinylene carbonate, fluoroethylene carbonate, 1,3-propane sultone, and an additive A. The additive A is a polynitrile six-membered nitrogen-heterocyclic compound with a relatively low oxidation potential. The lithium-ion battery has superb cycle performance and storage performance, especially under high-temperature and high-voltage conditions.

LITHIUM-ION BATTERY AND APPARATUS

The present application provides a lithium-ion battery and an apparatus, the lithium-ion battery includes an electrode assembly and an electrolyte. The electrode assembly includes a positive electrode sheet, a negative electrode sheet and a separation film. The positive active material in the positive electrode sheet includes Lix1Coy1M1-y1 O2-z1Qz1, 0.5≤x1≤1.2, 0.8≤y1≤1.0, 0≤z1≤0.1, and M is selected from one of Al, Ti, Zr, Y, and Mg, and Q is selected from one or more of F, Cl, and S. The electrolyte contains an additive A and an additive B, the additive A is a polynitrile six-membered nitrogen-heterocyclic compound with a relatively low oxidation potential, and the additive B is an aliphatic dinitrile or polynitrile compound with a relatively high oxidation potential. The lithium-ion battery of the present application has superb cycle performance and storage performance, especially under high-temperature and high-voltage conditions.

LITHIUM-ION BATTERY AND APPARATUS

The present application provides a lithium-ion battery and an apparatus, the lithium-ion battery includes an electrode assembly and an electrolyte, the electrode assembly includes a positive electrode sheet, a negative electrode sheet and a separator. A positive active material of the positive electrode sheet includes both Lix1Coy1M11-y1O2-aQ1a and LilNim1Con1M2pM3qO2-bQ2b, a mass ratio of Lix1Coy1M11-y1O2-aQ1a and LilNim1Con1M2pM3qO2-bQ2b is 1:1-9:1. The electrolyte contains an additive A, the additive A is a six-membered nitrogen heterocyclic compound with multiple nitrile groups and with low oxidation potential. The lithium-ion battery according to the present application has excellent cycle performance and storage performance, especially under high temperature and high voltage conditions.

ELECTROLYTE AND ELECTROCHEMICAL DEVICE

The present disclosure relates to the field of energy storage materials, and particularly, to an electrolyte and an electrochemical device. The electrolyte includes an additive A and an additive B, the additive A is selected from a group consisting of multi-cyano six-membered N-heterocyclic compounds represented by Formula I-1, Formula I-2 and Formula I-3, and combinations thereof, and the additive B is at least one unsaturated bond-containing cyclic carbonate compound. The electrochemical device includes the above electrolyte. The electrolyte of the present disclosure can effectively passivate surface activity of the positive electrode material, inhibit oxidation of the electrolyte, and effectively reduce gas production of the battery, while an anode SEI film can be formed to avoid a contact between the anode and the electrode and thus to effectively reduce side reactions.

ELECTROLYTE AND ELECTROCHEMICAL DEVICE

An electrolyte and an electrochemical device, which relates to the field of energy storage materials. The electrolyte includes an additive A, an additive B and an additive C, the additive A selected from a group consisting of multi-cyano six-membered N-heterocyclic compounds represented by Formula I-1, Formula I-2 or Formula I-3, and combinations thereof, the additive B is at least one sulfonate compound, and the additive C is at least one halogenated cyclic carbonate compound. The electrochemical device includes the above electrolyte. The electrolyte of the present disclosure can effectively passivate the surface activity of the positive electrode material, inhibit the oxidation of the electrolyte, and effectively reduce gas production of a battery, meanwhile the electrolyte can be also adsorbed catalytically active of the graphite surface to form a more stable SEI film, thereby effectively reducing side reactions

Preparation of Monomeric Methyleneaminoacetonitrile H2C=N-CH2-CN in the Gas Phase

The reactive intermediate methyleneaminoacetonitrile H2C=N-CH2-CN has been generated via thermal retrotrimerization of N,N',N''-tris(cyanomethyl)hexahydro-s-triazine and characterized by its photoelectron, mass and low-temperature NMR spectra.A fully geometry-optimized MNDO calculation allows to assign the observed ionization energies and yields estimates for other molecular properties, e.g. a rather high dipole moment. - Methyleneaminoacetonitrile Monomer and Trimer, Thermal Retrotrimerization, PE Spectra, MNDO Calculations, 1H NMR Spectra