4671-91-4Relevant academic research and scientific papers
ELECTROCHEMICAL REACTIONS OF S-, Se-, AND Te-CONTAINING ORGANIC COMPOUNDS. XXII. MECHANISM OF THE ANODIC FUNCTIONALIZATION OF OLEFINS
Zhuikov, V. V.,Latypova, V. Z.,Postnikova, M. Yu.,Kargin, Yu. M.
, p. 1195 - 1197 (2007/10/02)
In the anodic oxidation of 1-selenochromanone at a platinum electrode in acetonitrile primary radical cations are formed, and these have dual reactivity.The deprotonation of the radical cations leads to the formation of an α,β-unsaturated compound, as in the absence of cyclohexene.As a result of a parallel decyclization reaction (breakage of Csp3-Se bond) in the radical cation there occur allyl acetamidation and hydroxylation of the cyclohexene present in the anolyte by the selenation-deselenation mechanism.
