46997-98-2Relevant academic research and scientific papers
An efficient and recyclable ionic diphosphine-based Ir-catalyst for hydroaminomethylation of olefins with H2O as the hydrogen source
Liu, Huan,Yang, Da,Wang, Dong-Liang,Wang, Peng,Lu, Yong,Giang, Vo-Thanh,Liu, Ye
, p. 7979 - 7982 (2018)
Hydroaminomethylation of olefins with H2O as the hydrogen source was accomplished over an Ir-catalyst with the involvement of an ionic diphosphine (L6). The use of H2O as the hydrogen source could completely inhibit the hydrogenation
Decarboxylative C(sp3)?N cross-coupling of diacyl peroxides with nitrogen nucleophiles
Tang, Zi-Liang,Ouyang, Xuan-Hui,Song, Ren-Jie,Li, Jin-Heng
, p. 1000 - 1004 (2021/02/06)
We have disclosed a new radical-mediated decarboxylative C(sp3)?N cross-coupling of diacyl peroxides with nitrogen nucleophiles. The primary and secondary alkyl radicals derived from corresponding diacyl peroxides were generated by copper catalysis or by merging copper catalysis and photoredox catalysis, respectively. Various N-alkyl nitrogen nucleophiles, including indazoles, triazoles, indoles, purine, carbazole, anilines, and sulfonamide, were provided with a broad substrate scope and good functional group tolerance.
Free radical mediated decarboxylation C(sp3)-N cross-coupling reaction of diacyl peroxide and nitrogen-containing nucleophilic reagent
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Paragraph 0029-0041, (2021/05/15)
The invention discloses a free radical mediated decarboxylation C(sp3)-N cross coupling reaction method of diacyl peroxide and a nitrogen-containing nucleophilic reagent. According to the method, novel diacyl peroxide is used as an alkylation reagent, dif
