472-19-5

Basic information

• Product Name: (2,2-dimethyl-6-methylenecyclohexyl)methanol
• CAS NO: 472-19-5
• Molecular Weight: 154.252
• Mol File: 472-19-5.mol
• Article Data: 12

Chemical Properties

• CAS DataBase Reference: (2,2-dimethyl-6-methylenecyclohexyl)methanol(CAS DataBase Reference)
• NIST Chemistry Reference: (2,2-dimethyl-6-methylenecyclohexyl)methanol(472-19-5)
• EPA Substance Registry System: (2,2-dimethyl-6-methylenecyclohexyl)methanol(472-19-5)

Safety Data

• Hazardous Substances Data: 472-19-5(Hazardous Substances Data)

Upstream product

• 41641-14-9 1-hydroxymethyl-3,3-dimethyl-cyclohex-1-ene 
• 432-23-5 2,2-dimethyl-6-methylenecyclohexane-1-carbaldehyde 
• 65482-49-7 3-trimethylsilylmethyl-7-methyl-2,6-octadienoic acid 
• 81752-85-4 methyl (Z)-7-methyl-3-((trimethylsilyl)methyl)octa-2,6-dienoate 
• 50-00-0 formaldehyd 
• 91008-65-0 2-Hydroxymethyl-1,3,3-trimethyl-cyclohexanol 
• 73956-64-6 ethyl 2,2-dimethyl-6-methylenecyclohexane-1-carboxylate 
• 99182-73-7 2-(hydroxymethyl)-3,3-dimethylcyclohexan-1-one 
• 74-95-3 1,1-dibromomethane 
• 106-24-1 Geraniol 
• 1193-18-6 3-methylcyclohexen-2-one 
• 2979-10-4 ethyl 2,2-dimethyl-6-oxocyclohexane-1-carboxylate 
• 53067-23-5 methyl 7-methyl-3-oxooct-6-enoate 
• 88218-59-1 methyl (Z)-3-((diethoxyphosphoryl)oxy)-7-methylocta-2,6-dienoate 

Downstream Products

• 120931-39-7 (+/-)-γ-cyclogeranyl chloride 
• 188540-03-6 Methanesulfonic acid (S)-2,2-dimethyl-6-methylene-cyclohexylmethyl ester 
• 502763-33-9 (S)-(-)-2,2-dimethyl-6-methylene-1-[1'-(phenylthio)methyl]cyclohexane 
• 502763-34-0 (S)-1-[1′-benzenesulfonyl]methyl-2,2-dimehtyl-6-methylenecyclohexane 
• 924884-84-4 (S)-2,2-dimethyl-6-methylene-1-[3'-(1''-phenyl-1''H-tetrazole-5''-sulfanyl)butyl]cyclohexane 
• 924884-90-2 (S)-2,2-dimethyl-1-[3'-(benzothiazole-2''-sulfanyl)butyl]-6-methylenecyclohexane 
• 502763-37-3 (2E,6E)-9-((1S)-2,2-dimethyl-6-methylenecyclohexyl)-3,7-dimethyl-1-(tetrahydro-2-pyranyl)oxy-2,6-nonadiene 
• 145398-68-1 luffarin-P 
• 930649-65-3 (S)-(2,2-dimethyl-6-methylenecyclohexyl)methyl acetate 
• 930649-64-2 (R)-(2,2-dimethyl-6-methylenecyclohexyl)methyl acetate 
• 166022-29-3 (S)-(+)-(2',2'-dimethyl-6'-methylene-1'-cyclohexyl)methanol 
• 166022-33-9 ((R)-(-)-2,2-dimethyl-6-methylene-1-cyclohexyl)methanol 

Relevant articles and documents

Y-zeolite-catalyzed cyclizations of terpenols

Depending on the metal doped and the activation temperature, Y-zeolites can catalyze a diversity of reactions of geraniol (1), linalool (2) and nerol (3). Compound 1 can be transformed to α- and/or γ-cyclogeraniol (4 and 5) highly efficiently.

Synthesis of three putative kairomones of the beech leaf-mining weevil Orchestes fagi (L.)

The beech leaf-mining weevil, Orchestes fagi (L.), also known as the beech flea weevil, is a common and widespread pest of beech, Fagus sylvatica L., in its native Europe. It now appears to be well established in Nova Scotia, Canada. We report a novel synthesis of 9-geranyl-p-cymene and syntheses of 9-geranyl-α-terpinene and 1,1-dimethyl-3-methylene-2-vinylcyclohexane, making partial use of known methods. All three of these compounds are found in beech leaf volatiles and/or wood and are putative kairomones of the beech leaf-mining weevil.

Biomimetic cyclization of small terpenoids promoted by zeolite NaY: Tandem formation of α-ambrinol from geranyl acetone

Zeolite NaY promotes efficiently the biomimetic cyclization of small acyclic terpenes. Geranyl and neryl acetone undergo a novel tandem 1,5-diene cyclization/carbonyl-ene reaction to form the natural product α-ambrinol isolated in >65% yield.