472-78-6Relevant articles and documents
Transformations of α- And β-ionones in the presence of Al 2O3 in a supercritical solvent in a flow reactor
Anikeev,Sivcev,Volcho,Salakhutdinov
, p. 1940 - 1942 (2013/11/06)
The reactivity of α- and β-ionones under the supercritical conditions in a flow type reactor in the presence of Al2O3 at 200-230 C was studied. α-Ionone was reduced to α-ionol, while β-ionol was unstable already at 200 C and underwent dehydration. The secondary reaction products were the corresponding megastigmatrienes.
Chemoselective Hydrogen Transfer Reduction of Unsaturated Ketones to Allylic Alcohols with Solid Zr and Hf Catalysts
De Bruyn, Mario,De Vos, Dirk E.,Jacobs, Pierre A.
, p. 1120 - 1125 (2007/10/03)
α,β-Unsaturated ketones were reduced to allylic alcohols with high chemo- and diastereoselectivity, using Zr and Hf compounds heterogenised on mesoporous molecular sieves.