725739-83-3

Basic information

• Product Name: phosphoric acid diethyl ester (R)-2-iodo-4,4-dimethylcyclohex-2-enyl ester
• Synonyms: phosphoric acid diethyl ester (R)-2-iodo-4,4-dimethylcyclohex-2-enyl ester
• CAS NO: 725739-83-3
• Molecular Weight: 388.183
• Mol File: 725739-83-3.mol

Chemical Properties

• CAS DataBase Reference: phosphoric acid diethyl ester (R)-2-iodo-4,4-dimethylcyclohex-2-enyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: phosphoric acid diethyl ester (R)-2-iodo-4,4-dimethylcyclohex-2-enyl ester(725739-83-3)
• EPA Substance Registry System: phosphoric acid diethyl ester (R)-2-iodo-4,4-dimethylcyclohex-2-enyl ester(725739-83-3)

Safety Data

• Hazardous Substances Data: 725739-83-3(Hazardous Substances Data)

Upstream product

• 157952-85-7 2-iodo-4,4-dimethyl-cyclohex-2-enone 
• 1073-13-8 4,4-dimethylcyclohexenone 
• 814-49-3 diethyl chlorophosphate 
• 341497-26-5 (R)-4,4-dimethyl-2-iodo-2-cyclohexen-1-ol 

Downstream Products

• 903895-01-2 (S)-5,5-dimethyl-1-iodo-6-phenylcyclohexene 
• 1321556-47-1 (R)-5,5-dimethyl-6-(4-oxobutyl)cyclohex-1-enecarbaldehyde 
• 1321556-50-6 (R)-6-(3-(1,3-dioxolan-2-yl)propyl)-5,5-dimethylcyclohex-1-enecarbaldehyde 
• 1321556-48-2 (R)-2-(3-(2-iodo-6,6-dimethylcyclohex-2-en-1-yl)propyl)-1,3-dioxolane 
• 725740-03-4 ethyl 3-(2,6,6-trimethylcyclohex-2-en-1-yl)propanoate 
• 83059-15-8 (2E)-3-[(1R)-2,6,6-trimethyl-2-cyclohexen-1-yl]acrylaldehyde 
• 147379-73-5 (3)-<(R)-2,6,6-trimethl-2-cyclohexenyl>propanal 
• 472-78-6 α-ionol 
• 52567-56-3 (-)-α-Cyclogeranylethanol 
• 24190-29-2 (R)-α-ionone 
• 725739-85-5 (6R)-1-iodo-5,5-dimethyl-6-pentylcyclohex-1-ene 
• 725739-96-8 (R)-6-but-3-enyl-1-iodo-5,5-dimethylcyclohexene 
• 725739-97-9 (R)-3-(2-iodo-6,6-dimethylcyclohex-2-enyl)propionic acid ethyl ester 

Relevant articles and documents

Enantioselective synthesis of α-ionone derivatives using an anti SN2′ substitution of functionalized zinc organometallics

(Equation Presented) The allylic substitution of sterically hindered (2-iodocycloalkyl)phosphates proceeds with complete anti SN2′ stereoselectivity with mixed diorganozincs of the type RZnCH 2SiMe3 in the presence of CuCN·2LiCI. Only the group R of the copper-zinc reagent is transferred in the allylic substitution. This method was used to prepare odoriferous substances such as (R)-α-ionone in 97% ee and (R)-dihydro-α-ionone in 98% ee.