4792-39-6Relevant academic research and scientific papers
Room-temperature bismuth-catalyzed bis-arylation of carbonyl compounds with aryl ethers and phenols
Liu, Congrong,Li, Manbo
, p. 1274 - 1278 (2013/11/06)
Using Bi2(SO4)3 as the catalyst and TMSCl as the additive, a wide variety of aldehydes, ketones, and acetals were smoothly condensed with aryl ethers at room temperature to provide the corresponding diarylmethanes and triarylmethanes selectively in good to excellent yields. Using Bi2(SO4)3 as the catalyst and TMSCl as the additive, a wide variety of aldehydes, ketones, and acetals were smoothly condensed with aryl ethers at room temperature to selectively provide the corresponding diarylmethanes and triarylmethanes in good to excellent yields. Copyright
Catalytic selective bis-arylation of imines with anisole, phenol, thioanisole and analogues
Liu, Cong-Rong,Li, Man-Bo,Yang, Cui-Feng,Tian, Shi-Kai
, p. 1249 - 1251 (2008/12/21)
The first highly efficient double Friedel-Crafts reaction of N-tosyl imines with anisole, phenol, thioanisole and analogues has been developed to produce the corresponding symmetric diarylmethanes and triarylmethanes with high regioselectivity in the presence of a catalytic amount of Bi2(SO 4)3-TMSCl at room temperature. The Royal Society of Chemistry.
Dual-reagent catalysis within Ir-Sn domain: Highly selective alkylation of arenes and heteroarenes with aromatic aldehydes
Podder, Susmita,Choudhury, Joyanta,Roy, Ujjal Kanti,Roy, Sujit
, p. 3100 - 3103 (2008/02/05)
(Chemical Equation Presented) Reactions of arenes and heteroarenes with aromatic aldehydes proceeded smoothly in the presence of a catalytic combination of [Ir(COD)Cl]2-SnCl4 to afford the corresponding triarylmethane derivatives (TRAMs) in high yields. This 100% TRAM selective transformation is clean and eliminates the use of acid systems.
Activation conditions play a key role in the activity of zeolite CaY: NMR and product studies of Bronsted acidity
Kao, Hsien-Ming,Grey, Clare P.,Pitchumani, Kasi,Lakshminarasimhan,Ramamurthy
, p. 5627 - 5638 (2007/10/03)
CaY, activated under different conditions, was characterized with 1H, 31P, and 1H/27A] double resonance MAS NMR. The 1H MAS NMR spectra of CaY, calcined in an oven at 500 °C, shows resonances from H2O (bound to Ca2+ and the zeolite framework), CaOH+, aluminum hydroxides, silanols, and Bronsted acid sites. No evidence for Lewis acidity is observed on adsorption of trimethylphosphine, and an estimate of ≈16 Bronsted acid sites per unit cell is obtained for this sample. CaY activated in an oven at higher temperatures contains less water, but all the other species are still present. In contrast, CaY activated by slow ramping of the temperature under vacuum to 500 or 600 °C shows a much lower concentration of Bronsted acid sites (1/unit cell). Again, no evidence for Lewis acidity was observed. These NMR results have been utilized to understand the very different product distributions that are observed for reactions of 1,1- and 1,2-diarylethylenes in zeolite CaY activated in an oven (in air) and under vacuum. Samples with high concentrations of Bronsted acid sites react stoichiometrically with these sites, yielding diarylalkanes. At low concentrations, the Bronsted acid sites can act catalytically resulting in isomerization reactions.
Molybdenum-catalyzed aromatic substitution with olefins and alcohols
Shimizu, Isao,Khien, Kuok Meng,Nagatomo, Miki,Nakajima, Takayuki,Yamamoto, Akio
, p. 851 - 852 (2007/10/03)
A new type of electrophilic aromatic substitution without using organic halides has been realized by using Mo(CO)6 catalyst.
