4974-27-0 Usage
Definition
ChEBI: An alkadiene that is octane with the two double bonds located at positions 2 and 6.
Synthesis Reference(s)
Journal of the American Chemical Society, 73, p. 2654, 1951 DOI: 10.1021/ja01150a068
Check Digit Verification of cas no
The CAS Registry Mumber 4974-27-0 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 4,9,7 and 4 respectively; the second part has 2 digits, 2 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 4974-27:
(6*4)+(5*9)+(4*7)+(3*4)+(2*2)+(1*7)=120
120 % 10 = 0
So 4974-27-0 is a valid CAS Registry Number.
InChI:InChI=1/C8H14/c1-3-5-7-8-6-4-2/h3-6H,7-8H2,1-2H3/b5-3+,6-4+
4974-27-0Relevant articles and documents
REACTIONS INVOLVING TRANSITION METALS. XVII. REACTION OF ORGANIC HALOGEN COMPOUNDS WITH 2 AND 2 (S = CH2Cl2, THF)
Booth, Brian L.,Casey, Geoffrey C.,Haszeldine, Robert N.
, p. 197 - 205 (2007/10/02)
The complexes 2 and 2 (S=CH2Cl2, THF) have been shown to react with CXCl3 (X=Cl, H) to form with generation of both dichlorocarbene and trichloromethyl radical.Reaction of 2 with CF3I, allyl- and benzyl-halides takes a different course giving organic coupling products and .The THF solvate complex also causes coupling of gem-dihalides, and dehalogenation of vic-dihalides to produce alkenes.Possible mechanisms for these reactions are discussed.
