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9H-Xanthen-9-one, 3-bromois a brominated derivative of xanthen-9-one with the molecular formula C13H9BrO and a molecular weight of 265.11 g/mol. It is a chemical compound known for its bright red fluorescence under ultraviolet light.

500286-36-2

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500286-36-2 Usage

Uses

Used in Fluorescent Dyes:
9H-Xanthen-9-one, 3-bromois used as a fluorescent dye for its bright red fluorescence under ultraviolet light, making it suitable for applications such as fluorescent microscopy, flow cytometry, and bioimaging.
Used in Synthesis of Organic Compounds:
9H-Xanthen-9-one, 3-bromois used in the synthesis of various organic compounds due to its unique chemical properties.
Used in Production of Fluorescent Materials:
9H-Xanthen-9-one, 3-bromois used in the production of fluorescent materials, including optical brighteners and other research and industrial processes.
Used in Medical Diagnostics:
9H-Xanthen-9-one, 3-bromohas potential applications in medical diagnostics, where its fluorescent properties can be utilized for imaging and detection purposes.
Used in Drug Discovery:
9H-Xanthen-9-one, 3-bromocan be used in drug discovery for the development of new pharmaceutical compounds, taking advantage of its fluorescent properties for tracking and analysis.
Used in Environmental Monitoring:
9H-Xanthen-9-one, 3-bromohas potential applications in environmental monitoring, where its fluorescent properties can be used for detecting and analyzing contaminants and other substances in various environments.

Check Digit Verification of cas no

The CAS Registry Mumber 500286-36-2 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 5,0,0,2,8 and 6 respectively; the second part has 2 digits, 3 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 500286-36:
(8*5)+(7*0)+(6*0)+(5*2)+(4*8)+(3*6)+(2*3)+(1*6)=112
112 % 10 = 2
So 500286-36-2 is a valid CAS Registry Number.

500286-36-2Relevant academic research and scientific papers

Synthesis of xanthones from 4-(2-phenoxyphenyl)-1-tosyl-1H-1,2,3-triazole via rhodium-catalyzed annulation/oxidation

Anna,Chen, Zhaohang,Gao, Juanhong,Li, Chao,Qiao, Hongwei,Zhu, Mengyao

, (2021/10/19)

A series of xanthone derivatives were synthesized by rhodium-catalyzed cycloaddition and sequential oxidation. The derivatives synthesized for excellent yields, including electron-withdrawing and electron-donating substituents, demonstrated the wide applicability of the proposed approach. The xanthones synthesized with different substituent electron effects may go through the same intermediate via two cycloadditions. It is highlighted that the protocol was exemplified by its successful integration into a one-pot synthesis directly from 1-ethynyl-2-phenoxybenzene. We believe that the current method may be an attractive option for the synthesis of xanthone and its derivatives.

Formation and Disproportionation of Xanthenols to Xanthenes and Xanthones and Their Use in Synthesis

Shi, Zeyu,Chen, Si,Xiao, Qiong,Yin, Dali

, p. 3334 - 3343 (2021/02/05)

A facile and versatile strategy employing TiCl4-mediated cyclization followed by a Cannizzaro reaction has been developed for the synthesis of various xanthene derivatives. The reaction proceeded smoothly to afford both xanthenes/xanthones or their sulfur derivatives and tolerated a wide range of electronically diverse substrates. Using this methodology, pranoprofen was synthesized in three steps in 59% overall yield from commercially available starting materials.

Anthraquinone general formula compound and application thereof

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Paragraph 0046; 0048; 0053-0054, (2019/11/14)

The invention discloses an anthraquinone general formula compound and application thereof. The general formula compound is shown in a formula in the specification, in the formula, Y represents an oxygen atom or a sulfur atom, X1 to X8 represent C, CR or N

Anthraquinone organic electroluminescent material and application thereof

-

Paragraph 0058; 0060; 0065-0066, (2019/11/14)

The invention discloses an anthraquinone organic electroluminescent material and application thereof. A general formula compound is shown in a formula (1) in the specification, and in the formula (1),Z is selected from O or S; X1-X8 are independently selected from CR1 or N, wherein R1 is selected from a structure shown in a formula (2) in the specification, or selected from hydrogen, alkyl, arylor heterocyclic aryl, adjacent R1 groups can form a ring, and at least one of R1 groups is selected from the structure (2) shown in the formula (2); in the formula (2), Y1-Y8 are independently selected from CR2 or N, and at least one of the Y1-Y8 is selected from N; R2 is selected from hydrogen, alkyl, aryl or heterocyclic aryl, and adjacent R2 groups can form a ring; L is selected from single bonds, arylidene or heterocyclic arylidene; and when two or more R1 groups are selected from the formula (2), the selected L groups in the formula (2) are not single bonds at the same time. The compoundshows excellent device performance and stability when serving as the light-emitting material in an organic light-emitting device (OLED), and meanwhile the OLED adopting the general formula compound iswithin the scope of right protection.

Cu(0)/Selectfluor system-catalyzed intramolecular Csp2-H/Csp2-H cross-dehydrogenative coupling (CDC)

Bao, Hanyang,Hu, Xiaojun,Zhang, Jian,Liu, Yunkui

, (2019/09/30)

A Cu(0)/Selectfluor system-catalyzed intramolecular Csp2-H/Csp2-H bond cross-dehydrogenative coupling of 2-aryloxybenzaldehydes is described. A variety of substituted xanthone derivatives are synthesized in moderate to excellent yields. Reaction can also be extended to the synthesis of 9H-thioxanthen-9-one 10,10-dioxide and phenanthridin-6(5H)-ones, respectively.

Aza-spirofluorene anthracene heterocyclic compound and application thereof in organic electroluminescence elements

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Paragraph 0085; 0089; 0090, (2019/01/08)

The invention relates to an aza-spirofluorene anthracene heterocyclic compound and an application thereof in organic electroluminescence elements. The aza-spirofluorene anthracene heterocyclic compound is represented by a general formula (1) (shown in the description), wherein groups of furan, carbazole, thiophene, fluorine, heteraryl amino, acridine, phenazine and the like are linked to a matrixof the compound. According to the aza-spirofluorene anthracene heterocyclic compound, the transmission property of a current carrier can be improved, the triplet state energy of a material can be improved, the HOMO/LUMO value of the material can be optimized, the high brightness, low voltage, high efficiency and long service life of an organic EL element can be realized, meanwhile, the material prepared from the compound has relatively high heat stability, the luminescence stability of a light emitting device can be remarkably improved, and the compound can be widely used as a luminescent layer main body material for OLED light emitting devices and display devices.

High-efficiency long-service life organic room-temperature phosphorescence material and preparation method thereof

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Paragraph 0053; 0055, (2019/01/08)

The invention provides an alkoxy, benzyloxy or bromine substituted xanthone derivative and a preparation method thereof. The xanthone derivative is simple in preparation method, has a phosphorescencepeak on a long wavelength peak and is long in phosphorescence service life and high in light emission efficiency. The preparation method of the xanthone derivative comprises the following preparationsteps: 1, putting phenol, potassium carbonate, DMF (Dimethyl Formamide) and methylbenzene into a reaction container, backflowing for 3-5 hours in a nitrogen environment, and carrying out dehydration treatment till the system has no water generation; removing the methylbenzene, recovering to the room temperature, adding 4-bromine-2-fluorobenzonitrile, backflowing for 3-5 hours in the nitrogen environment, after the reaction is completed, diluting the solution with 100mL of methylbenzene, filtering, washing with water, drying so as to obtain a crude product of a crystal, and purifying with a spectrum column so as to obtain an intermediate as shown in the specification; 2, mixing the intermediate obtained in the step 1 with water and sulfuric acid, heating to 150-200 DEG C in the nitrogen environment, stirring, and backflowing for 10-15 hours; after the reaction is completed, cooling to the room temperature, diluting with water, extracting by using trichloromethane and a saturated sodiumchloride solution, combining organic phases, drying, filtering, carrying out vacuum distillation so as to remove the solvent and obtain a crude product of a crystal, and purifying with a spectrum column, so as to obtain an intermediate as shown in the specification.

Organic electroluminescence material and organic photoelectric device

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Paragraph 0087; 0088, (2017/07/21)

The invention provides a compound with a structure as shown in formula I. The invention also provides an application of the compound in an organic photoelectric device and the organic photoelectric device. The compound provided by the invention has a ther

Light emitting material, delayed fluorescent emitter, organic light emitting device, and compound

-

, (2017/07/06)

A compound represented by the following general formula is useful as a light emitting material. X represents an oxygen atom or a sulfur atom. R1 to R8 represent a hydrogen atom or a substituent, provided that at least one of R1

Rhodium-catalyzed xanthone formation from 2-aryloxybenzaldehydes via cross-dehydrogenative coupling (CDC)

Wang, Ping,Rao, Honghua,Hua, Ruimao,Li, Chao-Jun

supporting information; scheme or table, p. 902 - 905 (2012/04/05)

A concise and straightforward strategy to construct a xanthone skeleton via an intramolecular cross-dehydrogenative coupling (CDC) of 2- aryloxybenzaldehydes has been developed. The reaction proceeded smoothly without any need of preactivation of the aldehyde group. It can tolerate various functional groups and provides an applicable protocol to construct a wide range of xanthone derivatives.

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