50465-60-6

Basic information

• Product Name: 9-(2,6,6-Trimethyl-cyclohex-1-enyl)-5-phenyl-sulphonyl-3,7-dimethyl-1-acetoxy-nona-2,6,8-triene
• Synonyms: 9-(2,6,6-Trimethyl-cyclohex-1-enyl)-5-phenyl-sulphonyl-3,7-dimethyl-1-acetoxy-nona-2,6,8-triene
• CAS NO: 50465-60-6
• Molecular Weight: 470.673
• Mol File: 50465-60-6.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 9-(2,6,6-Trimethyl-cyclohex-1-enyl)-5-phenyl-sulphonyl-3,7-dimethyl-1-acetoxy-nona-2,6,8-triene(CAS DataBase Reference)
• NIST Chemistry Reference: 9-(2,6,6-Trimethyl-cyclohex-1-enyl)-5-phenyl-sulphonyl-3,7-dimethyl-1-acetoxy-nona-2,6,8-triene(50465-60-6)
• EPA Substance Registry System: 9-(2,6,6-Trimethyl-cyclohex-1-enyl)-5-phenyl-sulphonyl-3,7-dimethyl-1-acetoxy-nona-2,6,8-triene(50465-60-6)

Safety Data

• Hazardous Substances Data: 50465-60-6(Hazardous Substances Data)

Upstream product

• 1191-16-8 3-methylbut-2-enyl acetate 
• 38987-91-6 5-(2,6,6-trimethyl-cyclohex-1-enyl)-3-methyl-1-phenyl-sulphonyl-penta-2,4-diene 
• 59057-30-6 (1E)-1-(2,6,6-trimethylcyclohex-1-enyl)-3-methyl-1,4-pentadien-3-ol 
• 873-55-2 sodium benzenesulfonate 
• 114506-04-6 -4-Brom-1-chlor-2-methyl-2-buten 
• 52449-25-9 (6E,8E)-5-Benzenesulfonyl-3,7-dimethyl-9-(2,6,6-trimethyl-cyclohex-1-enyl)-nona-1,6,8-trien-3-ol 
• 108-24-7 acetic anhydride 
• 24529-80-4 (E)-1-O-acetyl-4-chloro-3-methyl-2-buten-1-ol 

Downstream Products

• 68-26-8 RETINOL 

Relevant articles and documents

Highly Efficient and General Synthetic Method of Various Retinyl Ethers

Bromination of 4 by PBr3 under Cu(I) catalyst produces the ambidextrous allylic halide 5 regioselectively and stereoselectively. Hetero nucleophiles distinguish the allylic carbon containing Br from the one containing Cl in 5 to give the heteroatom-substituted C5 allylic chloride 3. The Julia olefination reaction with the C15 sulfone 2 provides diverse retinyl ethers 1.

Synthesis with sulphones. IX. Synthesis of γ hydroxysulphones and of terpenic alcohols, linalool, nerolidol, isophytol, vitamin A

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