505-21-5

Usage

Uses

Used in Pharmaceutical Industry:
Hexahydro-pyrimidine is used as a key building block for the production of various pharmaceuticals, including antihistamines, antifungal agents, and anti-tumor drugs. Its versatile properties allow it to be incorporated into the molecular structures of these medications, enhancing their therapeutic effects.
Used in Agricultural Chemical Industry:
Hexahydro-pyrimidine also serves as an intermediate in the synthesis of pesticides and herbicides. Its presence in these compounds contributes to their effectiveness in controlling pests and unwanted plant growth, thereby supporting agricultural productivity.
Used in Polymer Synthesis:
Hexahydro-pyrimidine has potential applications in the synthesis of polymers. Its incorporation into polymer structures can impart specific properties, such as enhanced stability or reactivity, making these polymers suitable for various applications.
Used in Surface Active Agents:
Additionally, hexahydro-pyrimidine is utilized in the synthesis of surface active agents. These agents, which can alter the surface tension of liquids, are used in a wide range of products, including detergents, emulsifiers, and dispersants, due to their ability to improve the performance and efficiency of these formulations.

Upstream product

• 50-00-0 formaldehyd 
• 10517-44-9 1,3-diaminopropane dihydrochloride 
• 289-95-2 PYRIMIDINE 
• 109-76-2 Trimethylenediamine 
• 7647-01-0 hydrogenchloride 
• 41613-26-7 1,3-dimethyl-5-nitrouracil 

Downstream Products

• 15937-64-1 1,3-dibenzoylhexahydropyrimidine 
• 77215-44-2 1,3-bis(2-cyanoethyl)hexahydropyrimidine 
• 867065-85-8 tert-butyl tetrahydropyrimidin-1(2H)-carboxylic acid 
• 116046-92-5 1,3-dipivaloylhexahydropyrimidine 
• 1108169-89-6 8-chloro-2-(tetrahydropyrimidin-1(2H)-ylmethyl)[1]benzothieno[3,2-d]pyrimidin-4(3H)-one 
• 13090-31-8 1,5-Diazabicyclo[3.1.0]hexane 
• 50-00-0 formaldehyd 
• 109-76-2 Trimethylenediamine 

Relevant academic research and scientific papers

LITHIUM-ION BATTERY AND APPARATUS

This application provides a lithium-ion battery and an apparatus. The lithium-ion battery includes an electrode assembly and an electrolyte. The electrode assembly includes a positive electrode plate, a negative electrode plate, and a separator. A positive active material of the positive electrode plate includes Lix1Coy1M1-y1O2-z1Qz1, where 0.5≤x1≤1.2, 0.8≤y1≤1.0, 0≤z1≤0.1, M is selected from one or more of Al, Ti, Zr, Y, and Mg, and Q is selected from one or more of F, Cl, and S. The electrolyte contains an additive A, an additive B, and an additive C. The additive A is a polynitrile six-membered nitrogen-heterocyclic compound with a relatively low oxidation potential. The additive B is a silyl phosphite compound or a silyl phosphate compound or a mixture thereof. The additive C is a halogen substituted cyclic carbonate compound.

Lithium-ion battery and apparatus

This application provides a lithium-ion battery and an apparatus. The lithium-ion battery includes an electrode assembly and an electrolyte. The electrode assembly includes a positive electrode plate, a negative electrode plate, and a separator. A positive active material of the positive electrode plate includes Lix1Coy1M1-y1O2-z1Qz1, where 0.5≤x1≤1.2, 0.8≤y11.0, 0≤z1≤0.1, M is selected from one or more of Al, Ti, Zr, Y, and Mg, and Q is selected from one or more of F, Cl, and S. The electrolyte contains an additive A, an additive B, and an additive C. The additive A is a polynitrile six-membered nitrogen-heterocyclic compound with a relatively low oxidation potential. The additive B is an anhydride compound. The additive C is a halogen substituted cyclic carbonate compound.

LITHIUM-ION BATTERY AND APPARATUS

This application provides a lithium-ion battery and an apparatus. The lithium-ion battery includes an electrode assembly and an electrolyte. The electrode assembly includes a positive electrode plate, a negative electrode plate, and a separator. A positive active material of the positive electrode plate includes Lix1Coy1M1-y1O2-z1Qz1, where 0.5≤x1≤1.2, 0.8≤y1≤1.0, 0≤z1≤0.1, M is selected from one or more of Al, Ti, Zr, Y, and Mg, and Q is selected from one or more of F, Cl, and S. The electrolyte contains an additive A that is a polynitrile six-membered nitrogen-heterocyclic compound with a relatively low oxidation potential. The lithium-ion battery has superb cycle performance and storage performance, especially under high-temperature and high-voltage conditions.

LITHIUM-ION BATTERY AND APPARATUS

The present application provides a lithium-ion battery and an apparatus, and the lithium-ion battery includes an electrode assembly and an electrolytic solution, the electrode assembly includes a positive electrode sheet, a negative electrode sheet and a separation film. A positive active material of the positive electrode sheet includes Lix1Coy1M1-yO2-z1Qz1, 0.5≤x1≤1.2, 0.8≤y1≤1.0, 0≤z1≤0.1, M is selected from one or more of Al, Ti, Zr, Y, and Mg, and Q is selected from one or more of F, Cl, and S. The electrolytic solution contains vinylene carbonate, fluoroethylene carbonate, 1,3-propane sultone, and an additive A. The additive A is a polynitrile six-membered nitrogen-heterocyclic compound with a relatively low oxidation potential. The lithium-ion battery has superb cycle performance and storage performance, especially under high-temperature and high-voltage conditions.

LITHIUM-ION BATTERY AND APPARATUS

The present application provides a lithium-ion battery and an apparatus, the lithium-ion battery includes an electrode assembly and an electrolyte. The electrode assembly includes a positive electrode sheet, a negative electrode sheet and a separation film. The positive active material in the positive electrode sheet includes Lix1Coy1M1-y1 O2-z1Qz1, 0.5≤x1≤1.2, 0.8≤y1≤1.0, 0≤z1≤0.1, and M is selected from one of Al, Ti, Zr, Y, and Mg, and Q is selected from one or more of F, Cl, and S. The electrolyte contains an additive A and an additive B, the additive A is a polynitrile six-membered nitrogen-heterocyclic compound with a relatively low oxidation potential, and the additive B is an aliphatic dinitrile or polynitrile compound with a relatively high oxidation potential. The lithium-ion battery of the present application has superb cycle performance and storage performance, especially under high-temperature and high-voltage conditions.

LITHIUM-ION BATTERY AND APPARATUS

The present application provides a lithium-ion battery and an apparatus, the lithium-ion battery includes an electrode assembly and an electrolyte, the electrode assembly includes a positive electrode sheet, a negative electrode sheet and a separator. A positive active material of the positive electrode sheet includes both Lix1Coy1M11-y1O2-aQ1a and LilNim1Con1M2pM3qO2-bQ2b, a mass ratio of Lix1Coy1M11-y1O2-aQ1a and LilNim1Con1M2pM3qO2-bQ2b is 1:1-9:1. The electrolyte contains an additive A, the additive A is a six-membered nitrogen heterocyclic compound with multiple nitrile groups and with low oxidation potential. The lithium-ion battery according to the present application has excellent cycle performance and storage performance, especially under high temperature and high voltage conditions.

ELECTROLYTE AND ELECTROCHEMICAL DEVICE

The present disclosure relates to the field of energy storage materials, and particularly, to an electrolyte and an electrochemical device. The electrolyte includes an additive A and an additive B, the additive A is selected from a group consisting of multi-cyano six-membered N-heterocyclic compounds represented by Formula I-1, Formula I-2 and Formula I-3, and combinations thereof, and the additive B is at least one unsaturated bond-containing cyclic carbonate compound. The electrochemical device includes the above electrolyte. The electrolyte of the present disclosure can effectively passivate surface activity of the positive electrode material, inhibit oxidation of the electrolyte, and effectively reduce gas production of the battery, while an anode SEI film can be formed to avoid a contact between the anode and the electrode and thus to effectively reduce side reactions.

ELECTROLYTE AND ELECTROCHEMICAL DEVICE

An electrolyte and an electrochemical device, which relates to the field of energy storage materials. The electrolyte includes an additive A, an additive B and an additive C, the additive A selected from a group consisting of multi-cyano six-membered N-heterocyclic compounds represented by Formula I-1, Formula I-2 or Formula I-3, and combinations thereof, the additive B is at least one sulfonate compound, and the additive C is at least one halogenated cyclic carbonate compound. The electrochemical device includes the above electrolyte. The electrolyte of the present disclosure can effectively passivate the surface activity of the positive electrode material, inhibit the oxidation of the electrolyte, and effectively reduce gas production of a battery, meanwhile the electrolyte can be also adsorbed catalytically active of the graphite surface to form a more stable SEI film, thereby effectively reducing side reactions

Selective hydrogenation of N-heterocyclic compounds using Ru nanocatalysts in ionic liquids

N-Heterocyclic compounds have been tested in the selective hydrogenation catalysed by small 1-3 nm sized Ru nanoparticles (NPs) embedded in various imidazolium based ionic liquids (ILs). Particularly a diol-functionalised IL shows the best performance in the hydrogenation of quinoline to 1,2,3,4-tetrahydroquinoline (1THQ) with up to 99% selectivity.

An ATR-FTIR study on the effect of molecular structural variations on the CO2 absorption characteristics of heterocyclic amines, part II

This paper reports on an ATR-FTIR spectroscopic investigation of the CO2 absorption characteristics of a series of heterocyclic diamines: hexahydropyrimidine (HHPY), 2-methyl and 2,2-dimethylhexahydropyrimidine (MHHPY and DMHHPY), hexahydropyridazine (HHPZ), piperazine (PZ) and 2,5- and 2,6-dimethylpiperazine (2,6-DMPZ and 2,5-DMPZ). By using in situ ATR-FTIR the structure-activity relationship of the reaction between heterocyclic diamines and CO2 is probed. PZ forms a hydrolysis-resistant carbamate derivative, while HHPY forms a more labile carbamate species with increased susceptibility to hydrolysis, particularly at higher CO2 loadings (>0.5 mol CO2/mol amine). HHPY exhibits similar reactivity toward CO2 to PZ, but with improved aqueous solubility. The α-methyl-substituted MHHPY favours HCO3- formation, but MHHPY exhibits comparable CO2 absorption capacity to conventional amines MEA and DEA. MHHPY show improved reactivity compared to the conventional α-methyl- substituted primary amine 2-amino-2-methyl-1-propanol. DMHHPY is representative of blended amine systems, and its reactivity highlights the advantages of such systems. HHPZ is relatively unreactive towards CO 2. The CO2 absorption capacity CA (mol CO 2/mol amine) and initial rates of absorption RIA (mol CO2/mol amine min-1) for each reactive diamine are determined: PZ: CA=0.92, RIA=0.045; 2,6-DMPZ: C A=0.86, RIA=0.025; 2,5-DMPZ: CA=0.88, R IA=0.018; HHPY: CA=0.85, RIA=0.032; MHHPY: CA=0.86, RIA=0.018; DMHHPY: CA=1.1, R IA=0.032; and HHPZ: no reaction. Calculations at the B3LYP/6-31+G* and MP2/6-31+G* calculations show that the substitution patterns of the heterocyclic diamines affect carbamate stability, which influences hydrolysis rates. Copyright