cis,trans,cis-[Rh(H)2(PPh₃)2(methanol)2][PF₆]

Base Information

• Chemical Name: cis,trans,cis-[Rh(H)2(PPh₃)2(methanol)2][PF₆]
• CAS No.: 505048-61-3
• Molecular Formula: C₃₈H₄₀O₂P₂Rh*F₆P
• Molecular Weight: 838.552
• Mol file: 505048-61-3.mol

Synonyms:

Chemical Property of cis,trans,cis-[Rh(H)2(PPh₃)2(methanol)2][PF₆]

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of cis,trans,cis-[Rh(H)2(PPh₃)2(methanol)2][PF₆]

There total 1 articles about cis,trans,cis-[Rh(H)2(PPh₃)2(methanol)2][PF₆] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

methanol (67-56-1) + Shrock-Osborn catalyst (35238-97-2) + hydrogen (1333-74-0) → cis,trans,cis-[Rh(H)2(PPh3)2(methanol)2][PF6] (505048-61-3)

Guidance literature:

In methanol; suspn. of Rh-complex in MeOH was treated with 1 atm of H2 at room temp. for 2 h;

DOI:10.1021/om020992c

Reference yield: 75.0%

cis,trans,cis-[Rh(H)2(PPh3)2(methanol)2][PF6] (505048-61-3) + N-Benzylaniline (758640-21-0,103-32-2) → Rh(P(C6H5)3)2C6H5NHCH2C6H5(1+)*PF6(1-)=[Rh(C6H5NHCH2C6H5)(P(C6H5)3)2]PF6 (505048-63-5)

Guidance literature:

In methanol; under Ar; soln. of amine in MeOH was cannulated into soln. of Rh-complexin MeOH, stirred for 2 h at room temp.; vol. was reduced, ppt. sepd. and washed with Et2O, dried in vacuo; elem.anal.;

DOI:10.1021/om020992c

Reference yield:

cis,trans,cis-[Rh(H)2(PPh3)2(MeOH)2]PF6 (505048-61-3) + 2-Hydroxyphenylethylidenebenzylamine (5879-67-4) → [Rh(η-4-(C6H4O)C(CH3)N(H)CH2C6H5)(PPh3)2]PF6

Guidance literature:

In methanol; soln. of cis-(Rh(PPh3)2(MeOH)2)PF6 (0.09 mmol) in MeOH treated with (o-HOC6H4)C(Me)NCH2Ph (0.181 mmol) under Ar, mixt. stirred at room temp. for2 h; ppt. filtered off, washed (Et2O), vacuum-dried; elem. anal.;

DOI:10.1016/j.molcata.2006.04.012

upstream raw materials:

methanol

Shrock-Osborn catalyst

hydrogen

Downstream raw materials:

[Rh(P(C₆H₅)3)2(CD₃OD)(NH(CH₂C₆H₅)2)]⁽¹⁺⁾

Rh(P(C₆H₅)3)2C₆H₅NHCH₂C₆H₅⁽¹⁺⁾*PF₆^(1-)=[Rh(C₆H₅NHCH₂C₆H₅)(P(C₆H₅)3)2]PF₆