50789-44-1

Basic information

• Product Name: m-phenoxybenzyl acetate
• Synonyms: m-phenoxybenzyl acetate;3-PHENOXYBENZENEMETHANOL,ACETATE;3-Phenoxybenzyl=acetate
• CAS NO: 50789-44-1
• Molecular Formula: C₁₅H₁₄O₃
• Molecular Weight: 242.26986
• EINECS: 256-765-8
• Mol File: 50789-44-1.mol
• Article Data: 11

Chemical Properties

• Boiling Point: 338.8°C at 760 mmHg
• Flash Point: 140.2°C
• Appearance: /
• Density: 1.138g/cm³
• Vapor Pressure: 9.58E-05mmHg at 25°C
• Refractive Index: 1.558
• CAS DataBase Reference: m-phenoxybenzyl acetate(CAS DataBase Reference)
• NIST Chemistry Reference: m-phenoxybenzyl acetate(50789-44-1)
• EPA Substance Registry System: m-phenoxybenzyl acetate(50789-44-1)

Safety Data

• Hazardous Substances Data: 50789-44-1(Hazardous Substances Data)

Usage

InChI:InChI=1/C15H14O3/c1-12(16)17-11-13-6-5-9-15(10-13)18-14-7-3-2-4-8-14/h2-10H,11H2,1H3

Upstream product

• 3586-14-9 3-phenoxytoluene 
• 64-19-7 acetic acid 
• 802294-64-0 propionic acid 
• 108-05-4 vinyl acetate 
• 13826-35-2 3-Phenoxybenzyl alcohol 
• 108-24-7 acetic anhydride 
• 51632-16-7 3-phenoxybenzyl bromide 
• 127-09-3 sodium acetate 
• 21388-93-2 3-chlorobenzyl acetate 
• 108-95-2 phenol 

Downstream Products

• 39515-51-0 3-Phenoxybenzaldehyde 
• 13826-35-2 3-Phenoxybenzyl alcohol 

Relevant articles and documents

KMnO4-catalyzed chemoselective deprotection of acetate and controllable deacetylation-oxidation in one pot

A novel and efficient protocol for chemoselective deacetylation under ambient conditions was developed using catalytic KMnO4. The stoichiometric use of KMnO4 highlighted the dual role of a heterogeneous oxidant enabling direct access to aromatic aldehydes in one-pot sequential deacetylation-oxidation. The reaction employed an alternative solvent system and allowed the clean transformation of benzyl acetate to sensitive aldehyde in a single step while preventing over-oxidation to acids. Use of inexpensive and readily accessible KMnO4 as an environmentally benign reagent and the ease of the reaction operation were particularly attractive, and enabled the controlled oxidation and facile cleavage of acetate in a preceding step. This journal is

Silica-bonded N-propyl sulfamic acid as an efficient catalyst for the formylation and acetylation of alcohols and amines under heterogeneous conditions

A simple and efficient procedure for the preparation of silica-bonded N-propyl sulfamic acid (SBNPSA) by the reaction of 3-aminopropylsilica (1) and chlorosulfonic acid in chloroform is described. This solid acid is employed as a new catalyst for the formylation of alcohols and amines with ethyl formate under mild and heterogeneous conditions at room temperature with good to excellent yields. Also, SBNPSA catalyzed acetylation of various alcohols and amines with acetic anhydride at room temperature.

Thio-substituted tricyclic and bicyclic aromatic methanesulfinyl derivatives

The present invention is related to chemical compositions, processes for the preparation thereof and uses of the composition. Particularly, the present invention relates to compositions of compounds of Formula (A): wherein Ar, Y, R1 and q are as defined herein; and their use in the treatment of diseases, including treatment of sleepiness, promotion of wakefulness, treatment of Parkinson's disease, cerebral ischemia, stroke, sleep apneas, eating disorders, stimulation of appetite and weight gain, treatment of attention deficit hyperactivity disorder ("ADHD"), enhancing function in disorders associated with hypofunctionality of the cerebral cortex, including, but not limited to, depression, schizophrenia, fatigue, in particular, fatigue associated with neurologic disease, such as multiple sclerosis, chronic fatigue syndrome, and improvement of cognitive dysfunction.