51368-58-2

Basic information

• Product Name: isopropyl 1-bromocyclohexanecarboxylate
• Synonyms: isopropyl 1-bromocyclohexanecarboxylate
• CAS NO: 51368-58-2
• Molecular Weight: 249.148
• Mol File: 51368-58-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: isopropyl 1-bromocyclohexanecarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: isopropyl 1-bromocyclohexanecarboxylate(51368-58-2)
• EPA Substance Registry System: isopropyl 1-bromocyclohexanecarboxylate(51368-58-2)

Safety Data

• Hazardous Substances Data: 51368-58-2(Hazardous Substances Data)

Upstream product

• 2719-27-9 cyclohexanylcarbonyl chloride 
• 98-89-5 Cyclohexanecarboxylic acid 
• 29548-87-6 1-bromocyclohexanecarboxylic acid chloride 
• 67-63-0 isopropyl alcohol 

Downstream Products

• 1449522-52-4 isopropyl 2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)cyclohex-1-enecarboxylate 
• 472963-08-9 isopropyl (3R)-3-hydroxycyclohex-1-ene-1-carboxylate 
• 99438-50-3 (1S,3S)-3-hydroxycyclohexane-1-carboxylic acid isopropyl ester 
• 122689-79-6 isopropyl 3-oxocyclohex-1-ene-1-carboxylate 
• 472963-07-8 isopropyl 3-hydroxycyclohex-1-ene-1-carboxylate 
• 30434-55-0 isopropyl cyclohex-1-ene-1-carboxylate 

Relevant articles and documents

Chemoenzymatic synthesis of enantiopure isopropyl (3R)- and (3S)-3-hydroxycyclohex-1-ene-1-carboxylates and their reduction to isomers of isopropyl 3-hydroxy-cyclohexane-1-carboxylate

Reduction of an α,β-unsaturated cyclic ketone with Geotrichum candidum affords the corresponding (S)-allylic alcohol, while enantiospecific oxidation of the corresponding racemic alcohols leaves the (R)-enantiomer unchanged, giving access to both enantiomeric forms. Subsequent chemical reduction of the double bond of these homochiral allylic alcohol allows all isomers of the corresponding cyclohexanols to be obtained.