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52249-48-6

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52249-48-6 Usage

General Description

2-Quinolineacetic acid methyl ester is an organic compound with the formula C12H11NO2. It is a derivative of quinoline and is commonly used in the synthesis of pharmaceuticals and other organic compounds. This chemical is a colorless to slightly yellow liquid with a slightly pungent odor. It is insoluble in water but soluble in organic solvents such as ethanol and ether. It is known to have biological activity and is used in the development of new drugs and medical treatments. 2-Quinolineacetic acid methyl ester has potential applications in the pharmaceutical industry and in research laboratories for its unique properties and versatile chemistry.

Check Digit Verification of cas no

The CAS Registry Mumber 52249-48-6 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 5,2,2,4 and 9 respectively; the second part has 2 digits, 4 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 52249-48:
(7*5)+(6*2)+(5*2)+(4*4)+(3*9)+(2*4)+(1*8)=116
116 % 10 = 6
So 52249-48-6 is a valid CAS Registry Number.

52249-48-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 16, 2017

Revision Date: Aug 16, 2017

1.Identification

1.1 GHS Product identifier

Product name methyl 2-quinolin-2-ylacetate

1.2 Other means of identification

Product number -
Other names methyl 2-quinolinylacetate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:52249-48-6 SDS

52249-48-6Relevant articles and documents

Stereodivergent Allylation of Azaaryl Acetamides and Acetates by Synergistic Iridium and Copper Catalysis

Jiang, Xingyu,Boehm, Philip,Hartwig, John F.

supporting information, p. 1239 - 1242 (2018/02/09)

We report stereodivergent allylic substitution reactions of allylic esters with prochiral enolates derived from azaaryl acetamides and acetates to form products from addition of the enolates at the most substituted carbon of an allyl moiety with two catalysts, a chiral metallacyclic iridium complex and a chiral bisphosphine-ligated copper(I) complex, which individually control the configuration of the electrophilic and nucleophilic carbon atoms, respectively. By simple permutations of enantiomers of the two catalysts, all four stereoisomers of products containing two stereogenic centers were synthesized individually with high diastereoselectivity and enantioselectivity. A variety of azaaryl acetamides and acetates bearing pyridyl, benzothiazolyl, benzoxazolyl, pyrazinyl, quinolinyl and isoquinolinyl moieties were all found to be suitable for this transformation.

Rhodium-catalyzed NH insertion of pyridyl carbenes derived from pyridotriazoles: A general and efficient approach to 2-picolylamines and imidazo[1,5-a]pyridines

Shi, Yi,Gulevich, Anton V.,Gevorgyan, Vladimir

supporting information, p. 14191 - 14195 (2015/01/09)

A general and efficient NH insertion reaction of rhodium pyridyl carbenes derived from pyridotriazoles was developed. Various NH-containing compounds, including amides, anilines, enamines, and aliphatic amines, smoothly underwent the NH insertion reaction to afford 2-picolylamine derivatives. The developed transformation was further utilized in a facile one-pot synthesis of imidazo[1,5-a]pyridines.

Palladium-catalyzed decarboxylative couplings of 2-(2-Azaaryl)acetates with aryl halides and triflates

Shang, Rui,Yang, Zhi-Wei,Wang, Yan,Zhang, Song-Lin,Liu, Lei

supporting information; experimental part, p. 14391 - 14393 (2010/12/19)

Pd-catalyzed decarboxylative cross-couplings of 2-(2-azaaryl)acetates with aryl halides and triflates have been discovered. This reaction is potentially useful for the synthesis of some functionalized pyridines, quinolines, pyrazines, benzoxazoles, and benzothiazoles. Theoretical analysis shows that the nitrogen atom at the 2-position of the heteroaromatics directly coordinates to Pd(II) in the decarboxylation transition state.

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