52289-54-0

Basic information

• Product Name: 4-METHOXY-2-METHYLBENZALDEHYDE
• Synonyms: 4-METHOXY-2-METHYLBENZALDEHYDE;2-METHYL-P-ANISALDEHYDE;2-methyl-4-methoxybenzaldehyde;Benzaldehyde, 4-Methoxy-2-Methyl-;4-Methoxy-2-methylbenzaldehyde 95%
• CAS NO: 52289-54-0
• Molecular Formula: C₉H₁₀O₂
• Molecular Weight: 150.17
• Product Categories: Aromatic Aldehydes & Derivatives (substituted)
• Mol File: 52289-54-0.mol
• Article Data: 28

Chemical Properties

• Boiling Point: 262-267 °C(lit.)
• Flash Point: 230 °F
• Appearance: Pale yellow/Liquid
• Density: 1.107 g/mL at 25 °C(lit.)
• Vapor Pressure: 0.00987mmHg at 25°C
• Refractive Index: n20/D 1.571(lit.)
• Storage Temp.: Keep in dark place,Sealed in dry,Room Temperature
• CAS DataBase Reference: 4-METHOXY-2-METHYLBENZALDEHYDE(CAS DataBase Reference)
• NIST Chemistry Reference: 4-METHOXY-2-METHYLBENZALDEHYDE(52289-54-0)
• EPA Substance Registry System: 4-METHOXY-2-METHYLBENZALDEHYDE(52289-54-0)

Safety Data

• WGK Germany: 3
• Hazardous Substances Data: 52289-54-0(Hazardous Substances Data)

Usage

Chemical Properties

light yellow liquid

Synthesis Reference(s)

The Journal of Organic Chemistry, 49, p. 1078, 1984 DOI: 10.1021/jo00180a024Synthesis, p. 723, 1987

InChI:InChI=1/C9H10O2/c1-7-5-9(11-2)4-3-8(7)6-10/h3-6H,1-2H3

Upstream product

• 41438-18-0 4-hydroxy-2-methyl-benzaldehyde 
• 124-41-4 sodium methylate 
• 68-12-2 N,N-dimethyl-formamide 
• 100-84-5 1-methoxy-3-methyl-benzene 
• 77-78-1 dimethyl sulfate 
• 74-90-8 hydrogen cyanide 
• 52289-55-1 (4-methoxy-2-methylphenyl)methanol 
• 4685-47-6 3,4-dimethylanisole 
• 52289-56-2 1-(bromomethyl)-4-methoxy-2-methylbenzene 
• 72525-53-2 3-methoxybicyclo<4.2.0>octa-1(6),2,4-trien-7-ol 
• 123-11-5 4-methoxy-benzaldehyde 
• 74-88-4 methyl iodide 
• 27060-75-9 4-bromo-3-methylanisole 
• 557-21-1 dicyanozinc 

Downstream Products

• 80868-64-0 1-(4-Methoxy-2-methylphenyl)prop-2-en-1-ol 
• 100606-34-6 (2E)-3-(4-methoxy-2-methylphenyl)-2-propenoic acid 
• 142840-03-7 (E)-2-(4-methyl-3-pentenyl)-1-(2-nitro-1-butenyl)-4-methoxybenzene 
• 50-28-2 (+/-)-estradiol 
• 966-46-1 rac-3-Methoxy-1,3,5⁽¹⁰⁾,9⁽¹¹⁾-oestratetraen-17-on 
• 734-32-7 dl-estr-4-ene-3,17-dione 
• 75863-25-1 2-Trimethylsilyl-1-(4-methoxy-2-methylphenyl)prop-2-en-1-on 
• 80868-66-2 1-(4-Methoxy-2-methylphenyl)prop-2-en-1-on 
• 80868-76-4 3-Methoxy-1-(4-methoxy-2-methylphenyl)-1-propanon 
• 80868-74-2 1-(4-Methoxy-2-methylphenyl)-3-<(1Ξ,3Ξ,4SR)-3-methyl-2-oxo-4-vinylcyclopentyl>propan-1-on 
• 80868-77-5 rac-6,6,6-Trideuterio-3-methoxy-6,7:8,9-diseco-1,3,5⁽¹⁰⁾,7-oestratetraen-9,17-dion 
• 80868-73-1 rac-3-Methoxy-11ξ-trimethylsilyl-6,7:8,9-diseco-1,3,5(10),7-oestratetraen-9,17-dion 
• 80868-78-6 rac-11,11,16,16-Tetradeuterio-3-methoxy-6,7:8,9-diseco-1,3,5⁽¹⁰⁾,7-oestratetraen-9,17-dion 
• 80868-79-7 rac-6,6,6,11,11,16,16-Heptadeuterio-3-methoxy-6,7:8,9-diseco-1,3,5⁽¹⁰⁾,7-oestratetraen-9,17-dion 

Relevant articles and documents

Regiospecific Oxidation of Methyl Groups in Dimethylanisoles

Dimethylanisoles in which one of the methyl groups is meta and the other is ortho or para are regiospecifically oxidized in high yield to the corresponding ortho- and para-substituted aldehydes by copper(II) and peroxydisulfate.Subsequent oxidation of the

Volatiles from the xylarialean fungus Hypoxylon invadens

The volatiles emitted by agar plate cultures of the xylarialean fungus Hypoxylon invadens were investigated by use of a closed loop stripping apparatus in combination with GC-MS. Several aromatic compounds were found that could only be identified by comparison to all possible constitutional isomers with different ring substitution patterns. For the set of identified compounds a plausible biosynthetic scheme was suggested that gives further support for the assigned structures.

A 4-methoxy-2-methyl-benzyl cyanide synthesis method

The invention relates to a synthesis method for 4-methoxy-2-methyl benzyl cyanide. The synthesis method takes 3, 4-dimethylphenol which is cheap and simple and easy to purchase as the raw material, and comprises six steps: methylation, oxidation, Witting reaction, alkene ether hydrolysis, oximation and dehydration. The synthesis method uses the simple and cheap raw material, is simple to operate, is easy for industrial production, has short production cycle, only needs purification in the last step of the six so as to obtain high-quality 4-methoxy-2-methyl benzyl cyanide, and avoids using extremely toxic substances like NaCN and KCN, thus filling the blank home and abroad.