5244-75-7

Basic information

• Product Name: (phenylmethylene)-
• Synonyms: pentylcyclopropenone
• CAS NO: 5244-75-7
• Molecular Formula: C11H12
• Molecular Weight: 144.216
• Mol File: 5244-75-7.mol
• Article Data: 14

Chemical Properties

• CAS DataBase Reference: (phenylmethylene)-(CAS DataBase Reference)
• NIST Chemistry Reference: (phenylmethylene)-(5244-75-7)
• EPA Substance Registry System: (phenylmethylene)-(5244-75-7)

Safety Data

• Hazardous Substances Data: 5244-75-7(Hazardous Substances Data)

Upstream product

• 1191-95-3 cyclobutanone 
• 16721-45-2 triphenyl(phenylmethylene)phosphorane 
• 67-56-1 methanol 
• 82517-28-0 cyclobutylphenyldiazomethane 
• 57718-13-5 (5-bromo-pent-1-ynyl)-benzene 
• 34886-50-5 (5-iodopent-1-yn-1-yl)benzene 
• 3112-88-7 Benzyl phenyl sulfone 
• 6921-34-2 benzylmagnesium chloride 
• 7333-63-3 4-bromobutylphosphonium bromide 
• 100-52-7 benzaldehyde 
• 92078-64-3 11-bromo-5-undecyne 
• 5244-80-4 N,N-Dimethyl-α-phenyl-cyclobutyl-methylamin 
• 5407-98-7 1-cyclobutyl-1-phenyl-methanone 
• 73013-83-9 1-benzyl-1-hydroxycyclobutane 

Downstream Products

• 82833-97-4 (1-bromo-1-phenylmethylene)cyclobutane 
• 87957-41-3 1,1-Dichlor-2-phenylspiro<2.3>hexan 
• 100-52-7 benzaldehyde 
• 65-85-0 benzoic acid 
• 1127971-45-2 C₁₇H₁₅N₃O₂ 
• 5244-87-1 Essigsaeure-<(1-hydroxy-cyclobutyl)-phenyl-methylester> 
• 87957-47-9 1-Chlor-c-2-phenylspiro<2.3>hexan-r-1-carbonsaeure 
• 87957-47-9 1-Chlor-t-2-phenylspiro<2.3>hexan-r-1-carbonsaeure 
• 5244-85-9 (1-Hydroxy-cyclobutyl)-phenyl-methanol 
• 1198-34-1 2-Phenylcyclopentanone 
• 93714-50-2 1-Phenylspiro<2.3>hexane 
• 1322744-62-6 C₁₁H₁₃BrO 
• 1321621-46-8 C₁₁H₁₂O₂ 

Relevant articles and documents

Synthesis of 1-Pyrroline by Denitrogenative Ring Expansion of Cyclobutyl Azides under Thermal Conditions

We herein report an efficient and systematic synthesis of 1-pyrrolines from cyclobutyl azides under thermal and neutral conditions. The reaction proceeded without any additional reagents, and nitrogen was generated as the sole by-product. Furthermore, the generated 1-pyrrolines could be continuously transformed into pyrroles, N-Boc-amines, and oxaziridines in an one-pot manner. (Figure presented.).

Synthesis of multi-substituted cyclobutanes and alkylidenecyclobutanes by the reaction of cyclobutylmagnesium carbenoids with nucleophiles

Treatment of 1-chlorocyclobutyl p-tolyl sulfoxides with Grignard reagents such as ethylmagnesium chloride, isopropylmagnesium chloride, and cyclopentylmagnesium chloride in THF at low temperature gave cyclobutylmagnesium carbenoids in high yields. The gen

Enantioselective synthesis of 2-aryl cyclopentanones by asymmetric epoxidation and epoxide rearrangement

(Chemical Equation Presented) Optically active epoxides are prepared by the highly enantioselective epoxidation of benzylidenecyclobutanes using a glucose-derived ketone as the catalyst and oxone as the oxidant. A subsequent Lewis acid catalyzed rearrange