52667-89-7

Basic information

• Product Name: 1,4,7-tris[(4-Methylphenyl)sulfonyl]-1,4,7-triazonane
• Synonyms: 1,4,7-tris[(4-Methylphenyl)sulfonyl]-1,4,7-triazonane;1,4,7-Tritosyl-1,4,7-triazonane;1,4,7-tris(p-tolylsulfonyl)-1,4,7-triazacyclononane;1,4,7-Tri(p-tolylsulfonyl)-1,4,7-triazacyclononane;1,4,7-Tris(4-toluenesulfonyl)-1,4,7-triazacyclononane;1,4,7-Tris(p-toluenesulfonyl)-1,4,7-triazacyclononane;1,4,7-tris(phenylsulfonyl)-1,4,7-triazonane;1,4,7-Tritosyl-1,4,7-triazacyclononane
• CAS NO: 52667-89-7
• Molecular Formula: C₂₇H₃₃N₃O₆S₃
• Molecular Weight: 591.76242
• EINECS: 1312995-182-4
• Mol File: 52667-89-7.mol
• Article Data: 27

Chemical Properties

• Melting Point: 222-224℃
• Boiling Point: 749.407°C at 760 mmHg
• Flash Point: 407.027°C
• Appearance: /
• Density: 1.334g/cm³
• Vapor Pressure: 0mmHg at 25°C
• Refractive Index: 1.611
• Storage Temp.: Sealed in dry,Room Temperature
• PKA: -7.08±0.20(Predicted)
• CAS DataBase Reference: 1,4,7-tris[(4-Methylphenyl)sulfonyl]-1,4,7-triazonane(CAS DataBase Reference)
• NIST Chemistry Reference: 1,4,7-tris[(4-Methylphenyl)sulfonyl]-1,4,7-triazonane(52667-89-7)
• EPA Substance Registry System: 1,4,7-tris[(4-Methylphenyl)sulfonyl]-1,4,7-triazonane(52667-89-7)

Safety Data

• Hazardous Substances Data: 52667-89-7(Hazardous Substances Data)

Usage

General Description

1,4,7-tris[(4-Methylphenyl)sulfonyl]-1,4,7-triazonane is a chemical compound with the molecular formula C24H30N4O6S3. It is a complex structure consisting of three sulfonyl groups attached to a triazonane ring. 1,4,7-tris[(4-Methylphenyl)sulfonyl]-1,4,7-triazonane falls under the category of triazinanes, which are heterocyclic organic compounds containing nitrogen in the ring. The presence of the sulfonyl groups suggests that this chemical may have various uses in organic synthesis, potentially serving as a building block for the creation of other more complex compounds. Overall, 1,4,7-tris[(4-Methylphenyl)sulfonyl]-1,4,7-triazonane is a significant molecule with potential applications in various fields, including pharmaceuticals, materials science, and chemical research.

InChI:InChI=1/C27H33N3O6S3/c1-22-4-10-25(11-5-22)37(31,32)28-16-18-29(38(33,34)26-12-6-23(2)7-13-26)20-21-30(19-17-28)39(35,36)27-14-8-24(3)9-15-27/h4-15H,16-21H2,1-3H3

Upstream product

• 56187-04-3 1,4,7-tritosyl-1,4,7-triazaheptane 
• 106-93-4 ethylene dibromide 
• 6315-52-2 1,2-bis-tosyloxyethane 
• 98-59-9 p-toluenesulfonyl chloride 
• 111-40-0 3-azapentane-1,5-diamine 
• 4403-78-5 ditosylethylenediamine 
• 16695-22-0 N,N-bis(tosyloxyethyl)-p-toluenesulfonamide 
• 52601-80-6 N,N’,N”-tris(p-toluenesulfonyl)diethylenetriamine N,N-disodium salt 
• 115368-12-2 N³,N⁶-ditosyl-3,6-diaza-1,8-octanediol 
• 56234-52-7 1,8-bis(p-toluenesulfonyloxy)-3,6-bis(p-toluenesulfonyl)-3,6-diazaoctane 
• 70-55-3 toluene-4-sulfonamide 
• 99142-40-2 Toluene-4-sulfonic acid 2-[(toluene-4-sulfonyl)-(2-{(toluene-4-sulfonyl)-[2-(toluene-4-sulfonylamino)-ethyl]-amino}-ethyl)-amino]-ethyl ester 
• 1074-82-4 potassium phtalimide 

Downstream Products

• 58966-93-1 1,4,7-triazacyclononane trihydrochloride 
• 4730-54-5 1,4,7-triazacyclononane 
• 95388-08-2 N,N'-bis(p-toluenesulfonyl)-1,4,7-triazacyclononane 
• 96556-05-7 N,N',N''-trimethyl-1,4,7-triazacyclononane 
• 174138-01-3 1,4-di-tert-butyl 1,4,7-triazonane-1,4-dicarboxylate 
• 95388-12-8 1,3-bis[N,N'-bis(p-toluenesulfonyl)-1,4,7-triaza-1-cyclononyl]ethane 
• 1354021-90-1 1,4-di(tosyl)-1,4,7-triazacyclononane tosylate 
• 71771-37-4 hexahydro-2a,4a,6a-triaza-6b-phospha-cyclopenta[cd]pentalene 6b-oxide 
• 226917-73-3 4,10-bis-(toluene-4-sulfonyl)-1,4,7,10-tetraaza-bicyclo[5.5.2]tetradecane-2,6-dione 
• 226917-74-4 4,10-bis-(toluene-4-sulfonyl)-1,4,7,10-tetraaza-bicyclo[5.5.2]tetradecane 
• 157823-73-9 1,4-bis(p-tolylsulfonyl)-7-methyl-1,4,7-triazacyclononane 
• 112498-53-0 1-carboxaldehyde-1,4,7-triazacyclononane 
• 330804-76-7 1,4,7-tris(5-phenyl-4-pentynyl)-1,4,7-triazacyclononane 
• 176483-80-0 1,4-diisopropyl-7-(p-tolylsulfonyl)-1,4,7-triazacyclononane 

Relevant articles and documents

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Second-Sphere Interaction Promoted Turn-On Fluorescence for Selective Sensing of Organic Amines in a TbIII-based Macrocyclic Framework

Guided by a second-sphere interaction strategy, we fabricated a Tb(III)-based metal—organic framework (MMCF-4) for turn-on sensing of methyl amine with ultra-low detection limit and high turn-on efficiency. MMCF-4 features lanthanide nodes shielded in a nonacoordinate geometry along with secondary coordination spheres that are densely populated with H-bond interacting sites. Nonradiative routes were inhibited by binding-induced rigidification of the ligand on the second coordination sphere, resulting in luminescence amplification. Such remote interacting mechanism involved in the turn-on sensing event was confirmed by single-crystal X-ray diffraction and molecular dynamic simulation studies. The design of both primary and secondary coordination spheres of Tb(III) enabled the first turn-on sensing of organic amines in aqueous conditions. Our work suggests a promising strategy for high-performance turn-on sensing for Ln-MOFs and luminous materials driven by other metal chromophores.

METHOD FOR PREPARING NOTA DERIVATIVE

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