5267-27-6

Usage

InChI:InChI=1/C7H7N3O4/c1-4-2-5(8)7(10(13)14)3-6(4)9(11)12/h2-3H,8H2,1H3

Upstream product

• 64-17-5 ethanol 
• 5411-53-0 5-bromo-2,4-dinitro-toluene 
• 610-25-3 2,4,5-trinitrotoluene 
• 51676-74-5 1-chloro-5-methyl-2,4-dinitrobenzene 
• 98953-57-2 5-methyl-2,4-dinitro-phenetole 
• 2563-96-4 Trichlor-essigsaeure-m-toluidid 
• 103752-65-4 acetic acid-(5-methyl-2,4-dinitro-anilide) 
• 7664-41-7 ammonia 
• 537-92-8 3-Methylacetanilide 
• 7697-37-2 nitric acid 
• 52146-86-8 2,4-dinitro-5-methylbenzenesulfonic acid 
• 73334-04-0 3,5-Diamino-2,4,6-trinitrotoluene 
• 610-39-9 3,4-Dinitrotoluene 
• 619-15-8 2,5-dinitrotoluene 

Downstream Products

• 121-14-2 2,4-dinitrotoluene 
• 616-73-9 4,6-dinitro-3-hydroxytoluene 
• 103752-65-4 acetic acid-(5-methyl-2,4-dinitro-anilide) 
• 65958-37-4 4-methyl-5-nitrobenzene-1,2-diamine 
• 25917-89-9 4-amino-3-nitro-6-methylaniline 
• 5267-20-9 bis-(5-methyl-2,4-dinitro-phenyl)-diazene 
• 51676-74-5 1-chloro-5-methyl-2,4-dinitrobenzene 
• 102367-95-3 2-diazo-4-methyl-3,5-dinitrophenol 
• 122457-29-8 3,7-dimethyl-6-aminoquinoxaline 
• 97389-14-5 3,7-dimethyl-6-(N-methylamino)quinoxaline 
• 122457-27-6 4-methyl-5-nitro-2-(N-propargylamino)aniline 
• 122457-26-5 2,4-dinitro-5-(N-propargylamino)toluene 
• 61587-90-4 5-methyl-6-nitro-1(3)H-benzimidazole 
• 120209-26-9 2,5-Dimethyl-6-nitrobenzimidazole 

Relevant academic research and scientific papers

Bicyclic heterocyclic anthranilic diamides as ryanodine receptor modulators with insecticidal activity

The diamide insecticides act on the ryanodine receptor (RyR). The synthesis of various bicyclic anthranilic derivatives is reported. Their activity against the insect ryanodine receptor (RyR) and their insecticidal activity in the greenhouse is presented,

Amination of some 1,3-dinitrobenzenes with liquid ammonia-potassium permanganate

1,3-Dinitrobenzene and some its 2- and 4-substituted derivatives are dehydroaminated in a solution of potassium permanganate in liquid ammonia to give the corresponding mono- or diamino-1,3-dinitro-benzenes. Under the same conditions, 4-fluoro-1,3-dinitrobenzene is converted into 2,4-dinitroaniline via replacement of the fluorine atom, while 2,4-dinitrobenzaldehyde gives rise to 2,4-dinitrobenzamide.

Photoinduced Nitro-Nitrite Rearrangement of 5-Nitroquinoxalines

Unlike known o-nitro methyl derivatives of aromatic compounds, 6-methyl-5-nitro-, 2,3,6-trimethyl-5-nitro-, and 7-methyl-6-nitroquinoxaline and 1,6-dimethyl-5-nitroquinoxalinium perchlorate do not exhibit photochromism in aqueous-ethanolic solutions under conditions of flash photolysis with a time resolution of 50 μs. Under conditions of continuous photolysis, these 5-nitromethylquinoxaline derivatives and also 5-nitroquinoxaline undergo nitro-nitrite rearrangement to give 5-quinoxalinol derivatives with quantum yields ranging from 1 × 10-4 to 3 × 10-3; the efficiency of the photochemical reaction increases when irradiation is performed with a shorter-wave light. 6-Nitro derivatives do not form stable products of photochemical transformations under the same conditions.

Thermal Stability Studies on a Homologous Series of Nitroarenes

The thermal stabilities of a number of nitroarenes were examined in solution and in condensed phase.In general, increasing the number of nitro groups decreased thermal stability.Changing the substituent on 1-X-2,4,6-trinitrobenzene from X = H to NH2 to CH3 to OH accelerated decomposition; this effect was attributed to increased ease of intramolecular proton transfer to an ortho nitro group, thus weakening the carbon-nitrogen bond.In solution, the effect of increasing substitution from n = 1 to n = 3 on Xn(NO2)3C6H3-n was uniformly that of decreasing the thermal stability of the species.However, in condensed phase, results suggested that crystal habit may be more important than molecular structure; for X = Br, CH3, and NH2, the more substituted species was the more stable.