52711-91-8Relevant academic research and scientific papers
Temperature-Controlled Selectivity of Hydrogenation and Hydrodeoxygenation of Biomass by Superhydrophilic Nitrogen/Oxygen Co-Doped Porous Carbon Nanosphere Supported Pd Nanoparticles
Havener, Kaden,Huang, Kun,Wu, Wenjin,Xu, Yang,Yu, Haitao,Zhang, Li,Zhang, Meng
, (2022/03/08)
Selective hydrogenation and hydrodeoxygenation (HDO) of biomass to value-added products play a crucial role in the development of renewable energy resources. However, achieving a temperature-controlled selectivity within one catalytic system while retaining excellent hydrogenation and HDO performance remains a great challenge. Here, nitrogen/oxygen (N/O) co-doped porous carbon nanosphere derived from resin polymer spheres is synthesized as the host matrix to in situ encapsulate highly dispersed Pd nanoparticles (NPs). Through N/O co-doping, the defects on the surface of carbon structure can serve as active sites to promote substrate adsorption. After a facile H2O2 post-treatment process, the presence of abundant carboxyl groups on the porous carbon nanospheres can act as acidic sites to replace the use of acidic additives in the HDO process. Additionally, the increased surface oxygen-containing groups improve hydrophilicity to disperse catalysts in aqueous solutions. Owing to the unique highly dispersed Pd NPs and abundant surface defects, the Pd@APF-H2O2 (2.3?nm) catalysts exhibit excellent catalytic activity and temperature-controlled selectivity for hydrogenation and HDO products of biomass-derived vanillin.
Practical Ligand-Free Copper-Catalysed Short-Chain Alkoxylation of Unactivated Aryl Bromides
Guo, Ying,Fan, Xue-Min,Nie, Min,Liu, Hong-Wei,Liao, Dao-Hua,Pan, Xian-Dao,Ji, Ya-Fei
, p. 4744 - 4755 (2015/08/03)
An efficient and practical short-chain alkoxylation of unactivated aryl bromides has been developed with special attention focussed on the applicability of the reaction. Sodium alkoxide is used as the nucleophile, and the corresponding alcohol as the solvent. The reaction requires neither precious metals nor organic ligands. It uses a catalytic system consisting of copper(I) bromide as a catalyst, the corresponding alkyl formate as a noncontaminating cocatalyst, and lithium chloride as an additive. A wide range of substrates and test cases highlight the synthetic utility of the approach. Considering the commercial accessibility and affordability of the feedstocks, this protocol shows promise as a new alternative for the sustainable preparation of aryl alkyl ethers.
