5290-29-9Relevant articles and documents
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Bradley,Thomas
, p. 3404,3405, 3409 (1959)
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Production of acyloxysilane
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Paragraph 0059-0064, (2021/10/30)
[A] a method for producing functional chemicals useful as efficient acyloxysilane. The silanol Si-to-OH bond [a], in the presence of a catalyst, comprising the step of reacting a carboxylic acid anhydride, Si-to-OCO bond (OCO is, oxycarbonyl groups (=O) O-a C shown. ) Having an acyloxysilane manufacturing method, wherein the catalyst, or (2) (1) production of acid catalyst selected from the next acyloxysilane. (1) 3 - 15 Of the periodic table of the first group the first group element selected from the perchlorate salt, trifluoromethanesulfonic acid salt, a bis (trifluoromethanesulfonyl imide) salt, lithium hexafluorophosphate salt, chloride, or bromide; inorganic acids; or an organic acid. (2) Inorganic or organic solid acid compounds[Drawing] no
Silylation of O-H bonds by catalytic dehydrogenative and decarboxylative coupling of alcohols with silyl formates
Chauvier, Clément,Godou, Timothé,Cantat, Thibault
, p. 11697 - 11700 (2017/11/03)
The silylation of O-H bonds is a useful methodology in organic synthesis and materials science. While this transformation is commonly achieved by reacting alcohols with reactive chlorosilanes or hydrosilanes, we show herein for the first time that silylformates HCO2SiR3 are efficient silylating agents for alcohols, in the presence of a ruthenium molecular catalyst.