5292-47-7

Basic information

• Product Name: DIMETHYL 2-FLUOROTEREPHTHALATE
• Synonyms: DIMETHYL 2-FLUOROTEREPHTHALATE;DIMETHYL FLUOROTEREPHTHALATE;2-FLUOROTEREPHTHALIC ACID DIMETHYL ESTER;Dimethyl 2-fluoroterephthalate 98%;Dimethyl2-fluoroterephthalate98%;2-fluorobenzene-1,4-dicarboxylic acid dimethyl ester;dimethyl 2-fluorobenzene-1,4-dicarboxylate
• CAS NO: 5292-47-7
• Molecular Formula: C₁₀H₉FO₄
• Molecular Weight: 212.17
• EINECS: 226-135-7
• Product Categories: Benzoic acid;Miscellaneous;C10 to C11;Carbonyl Compounds;Esters;Aryl Fluorinated Building Blocks;Building Blocks;C10 to C11;C8-C12;Carbonyl Compounds;Chemical Synthesis;Fluorinated Building Blocks;Organic Building Blocks;Organic Fluorinated Building Blocks;Other Fluorinated Organic Building Blocks
• Mol File: 5292-47-7.mol
• Article Data: 2

Chemical Properties

• Melting Point: 83-85 °C(lit.)
• Boiling Point: 80-90 °C0.35 mm Hg(lit.)
• Flash Point: 130.6 °C
• Appearance: /Powder
• Density: 1.252g/cm³
• Vapor Pressure: 0.00119mmHg at 25°C
• Refractive Index: 1.499
• Storage Temp.: Sealed in dry,Room Temperature
• CAS DataBase Reference: DIMETHYL 2-FLUOROTEREPHTHALATE(CAS DataBase Reference)
• NIST Chemistry Reference: DIMETHYL 2-FLUOROTEREPHTHALATE(5292-47-7)
• EPA Substance Registry System: DIMETHYL 2-FLUOROTEREPHTHALATE(5292-47-7)

Safety Data

• Hazard Codes: Xi
• Safety Statements: 24/25
• WGK Germany: 3
• HazardClass: IRRITANT
• Hazardous Substances Data: 5292-47-7(Hazardous Substances Data)

Usage

Chemical Properties

white to light yellow crystal powder

InChI:InChI=1/C10H9FO4/c1-14-9(12)6-3-4-7(8(11)5-6)10(13)15-2/h3-5H,1-2H3

Upstream product

• 350-28-7 3-fluoro-4-methyl-benzoic acid 
• 67-56-1 methanol 
• 3906-87-4 2-fluoro-1,4-benzenedicarboxylic acid 
• 201230-82-2 carbon monoxide 
• 348-59-4 1,4-dichloro-2-fluorobenzene 

Downstream Products

• 3906-87-4 2-fluoro-1,4-benzenedicarboxylic acid 
• 825650-06-4 2-(2-bromo-phenoxy)-terephthalic acid dimethyl ester 
• 214554-23-1 4-((E)-2-Ethoxycarbonyl-vinyl)-2-fluoro-benzoic acid benzyl ester 
• 214554-20-8 2-Fluoro-4-hydroxymethyl-benzoic acid benzyl ester 
• 214554-25-3 4-(2-Ethoxycarbonyl-ethyl)-2-fluoro-benzoic acid 
• 214554-39-9 2-Fluoro-4-formyl-benzoic acid benzyl ester 
• 214554-37-7 3-(3-Fluoro-4-hydroxymethyl-phenyl)-propionic acid ethyl ester 
• 5292-49-9 2-amino-5-fluoro-terephthalic acid dimethyl ester 
• 566158-06-3 2-fluoro-5-phenylamino-terephthalic acid dimethyl ester 
• 566158-69-8 2-fluoro-N-(2-(3-(methylthio)phenyl)propan-2-yl)-9-oxo-9,10-dihydroacridine-3-carboxamide 
• 566160-51-8 C₂₄H₂₁FN₂O₂S 
• 566158-07-4 2-fluoro-5-phenylamino-terephthalic acid 
• 5292-48-8 2-fluoro-5-nitro-terephthalic acid dimethyl ester 
• 161796-11-8 3-fluoro-terephthalic acid 4-methyl ester 

Relevant articles and documents

Defect Engineering into Metal-Organic Frameworks for the Rapid and Sequential Installation of Functionalities

Postsynthetic treatments are well-known and important functionalization tools of metal-organic frameworks (MOFs). Herein, we have developed a practical and rapid postsynthetic ligand exchange (PSE) strategy using a defect-controlled MOF. An increase in the number of defects amounts to MOFs with enhanced rates of ligand exchange in a shorter time frame. An almost quantitative exchange was achieved by using the most defective MOFs. This PSE strategy is a straightforward method to introduce a functionality into MOFs including bulky or catalytically relevant moieties. Furthermore, some mechanistic insights into PSE were revealed, allowing for a sequential ligand exchange and the development of multifunctional MOFs with controlled ligand ratios.