537030-25-4

Upstream product

• 537030-20-9 (2R,3R,4R)-2,3,5-tris(benzyloxy)-4-hydroxypentanal O-(tertbutyldiphenylsilyl)oxime 
• 537030-18-5 Methanesulfonic acid (1S,2S,3R)-2,3-bis-benzyloxy-1-benzyloxymethyl-4-(tetrahydro-pyran-2-yloxyimino)-butyl ester 
• 537030-17-4 (2R,3R,4S)-2,3,5-Tris-benzyloxy-4-hydroxy-pentanal O-(tetrahydro-pyran-2-yl)-oxime 
• 537030-19-6 (2R,3R,4R)-3,4-bis(benzyloxy)-2-((benzyloxy)methyl)-3,4-dihydro-2H-pyrrole 1-oxide 
• 16838-89-4 2,3,5-tri-O-benzyl-L-xylofuranose 
• 100-44-7 benzyl chloride 
• 41546-31-0 L-xylose 
• 160549-10-0 2,3,5-tri-O-benzyl-D-arabinofuranose 
• 532-20-7 D-arabinofuranose 
• 537030-24-3 (2R,3aR,4R,5R,6R)-4,5-bis(benzyloxy)-6-[(benzyloxy)methyl]-N,N-dimethylhexahydropyrrolo[1,2-b]isoxazole-2-carboxamide 

Downstream Products

• 847797-44-8 (1R,2R,3R,7aR)-1,2-bis(benzyloxy)-3-(benzyloxymethyl)-hexahydro-1H-pyrrolizine 
• 1227870-26-9 (2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-(1->6)-O-tris(benzyloxy)-7-deoxy-5-oxocasuarine 
• 537030-26-5 (1S,2R,3R,6R,7aR)-hexahydro-1,2-bis(phenylmethoxy)-3-[(phenylmethoxy)methyl]-1H-pyrrolizine-6-ol 
• 537030-27-6 (1R,2R,3R,6R,7aR)-1,2-bis-benzyloxy-3-benzyloxymethyl-6-metansulfonyloxy-hexahydro-1Hpyrrolizine 

Relevant academic research and scientific papers

Synthesis, biological evaluation and docking studies of casuarine analogues: Effects of structural modifications at ring B on inhibitory activity towards glucoamylase

We report the total synthesis of a series of pyrrolizidine analogues of casuarine (1) and their 6-O-α-glucoside derivatives. The synthetic strategy is based on a totally regio- and stereoselective 1,3-dipolar cycloaddition of suitably substitutedalkenes a

Total syntheses of hyacinthacine A2 and 7-deoxycasuarine by cycloaddition to a carbohydrate derived nitrone

Practical syntheses of nitrone 8 by two different approaches from sugars are reported. Its use as a versatile intermediate in highly selective 1,3-dipolar cycloaddition reactions constitutes the key step for novel total syntheses of hyacinthacine A2