537030-18-5

Upstream product

• 124-63-0 methanesulfonyl chloride 
• 537030-17-4 (2R,3R,4S)-2,3,5-Tris-benzyloxy-4-hydroxy-pentanal O-(tetrahydro-pyran-2-yl)-oxime 
• 16838-89-4 2,3,5-tri-O-benzyl-L-xylofuranose 
• 100-44-7 benzyl chloride 
• 41546-31-0 L-xylose 
• 6723-30-4 O-2-tetrahydro-2H-pyranhydroxylamine 

Downstream Products

• 537030-27-6 (1R,2R,3R,6R,7aR)-1,2-bis-benzyloxy-3-benzyloxymethyl-6-metansulfonyloxy-hexahydro-1Hpyrrolizine 
• 537030-24-3 (2R,3aR,4R,5R,6R)-4,5-bis(benzyloxy)-6-[(benzyloxy)methyl]-N,N-dimethylhexahydropyrrolo[1,2-b]isoxazole-2-carboxamide 
• 537030-25-4 (1R,2R,3R,6R,7aR)-1,2-bis(benzyloxy)-3-[(benzyloxy)methyl]-6-hydroxyhexahydro-5H-pyrrolizin-5-one 
• 537030-26-5 (1S,2R,3R,6R,7aR)-hexahydro-1,2-bis(phenylmethoxy)-3-[(phenylmethoxy)methyl]-1H-pyrrolizine-6-ol 
• 847797-44-8 (1R,2R,3R,7aR)-1,2-bis(benzyloxy)-3-(benzyloxymethyl)-hexahydro-1H-pyrrolizine 
• 537030-19-6 (2R,3R,4R)-3,4-bis(benzyloxy)-2-((benzyloxy)methyl)-3,4-dihydro-2H-pyrrole 1-oxide 

Relevant academic research and scientific papers

Total syntheses of hyacinthacine A2 and 7-deoxycasuarine by cycloaddition to a carbohydrate derived nitrone

Practical syntheses of nitrone 8 by two different approaches from sugars are reported. Its use as a versatile intermediate in highly selective 1,3-dipolar cycloaddition reactions constitutes the key step for novel total syntheses of hyacinthacine A2