537030-29-8

Upstream product

• 124-63-0 methanesulfonyl chloride 
• 169736-18-9 (2S,3R,4S)-3,4-bis(benzyloxy)-2-[(benzyloxy)methyl]-5-methoxyoxolane 
• 847797-40-4 C₄₂H₄₇NO₅Si 
• 16838-89-4 2,3,5-tri-O-benzyl-L-xylofuranose 

Downstream Products

• 847797-44-8 (1R,2R,3R,7aR)-1,2-bis(benzyloxy)-3-(benzyloxymethyl)-hexahydro-1H-pyrrolizine 
• 537030-28-7 (5R,6R,7R,7aR)-6,7-bis-benzyloxy-5-benzyloxymethylhexahydropyrrolizin-3-one 
• 537030-19-6 (2R,3R,4R)-3,4-bis(benzyloxy)-2-((benzyloxy)methyl)-3,4-dihydro-2H-pyrrole 1-oxide 

Relevant academic research and scientific papers

One-pot synthesis of cyclic nitrones and their conversion to pyrrolizidines: 7a-epi-crotanecine inhibits α-mannosidases

A new straightforward and inexpensive one-pot procedure is described for the preparation of enantiopure five-membered cyclic nitrones starting from the corresponding lactols. Its efficiency relies on the condensation of unprotected hydroxylamine with read

Total synthesis of (+)-hyacinthacine A2 based on SmI 2-induced nitrone umpolung

(Chemical Equation Presented) A concise total synthesis of (+)-hyacinthacine A2, a polyhydroxylated pyrrolizidine alkaloid, is described using our recently discovered inversion of the C-N bond polarity in nitrones. In the key step, the diastere