5445-29-4

Basic information

• Product Name: ETHYL 2-BROMOOCTANOATE
• Synonyms: Octanoic acid, 2-bromoethyl ester;ETHYL 2-BROMOOCTANOATE;ETHYL 2-BROMOCAPRYLATE;α-Bromo-octanoic acid ethyl ester;Ethyl 2-bromooctanoate, 98+%;Ethyl 2-caprylate;ALPHA-BROMO-OCTANOIC ACID ETHYL ESTER;Ethyl 2-BroMooCLanoate
• CAS NO: 5445-29-4
• Molecular Formula: C10H19BrO2
• Molecular Weight: 251.16
• EINECS: 226-647-0
• Product Categories: Building Blocks;C10 to C11;Carbonyl Compounds;Chemical Synthesis;Esters;Organic Building Blocks
• Mol File: 5445-29-4.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 137-140 °C25 mm Hg(lit.)
• Flash Point: 224 °F
• Appearance: /
• Density: 1.167 g/mL at 25 °C(lit.)
• Vapor Pressure: 0.0327mmHg at 25°C
• Refractive Index: n20/D 1.452(lit.)
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• BRN: 1767535
• CAS DataBase Reference: ETHYL 2-BROMOOCTANOATE(CAS DataBase Reference)
• NIST Chemistry Reference: ETHYL 2-BROMOOCTANOATE(5445-29-4)
• EPA Substance Registry System: ETHYL 2-BROMOOCTANOATE(5445-29-4)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36
• RIDADR: UN 3334
• WGK Germany: 3
• F: 19
• Hazardous Substances Data: 5445-29-4(Hazardous Substances Data)

Usage

General Description

Ethyl 2-bromooctanoate is a chemical compound with the molecular formula C10H19BrO2. It is a colorless or pale yellow liquid with a fruity odor, and it is commonly used as a flavoring agent and fragrance ingredient. It is also used as an intermediate in the production of pharmaceuticals and pesticides. Ethyl 2-bromooctanoate is a versatile chemical that has applications in various industries, and it is important to handle it with caution as it is flammable and may cause skin and eye irritation upon contact.

InChI:InChI=1/C10H19BrO2/c1-3-5-6-7-8-9(11)10(12)13-4-2/h9H,3-8H2,1-2H3/t9-/m1/s1

Upstream product

• 64-17-5 ethanol 
• 2623-82-7 2-bromooctanoic acid 
• 7664-93-9 sulfuric acid 
• 106265-08-1 2-bromooctanoyl bromide 
• 83818-62-6 1-chloro-1-(phenylthio)-1-octene 
• 59176-56-6 1-Methylthio-1-(trimethylsilyl)-1-octen 
• 124-07-2 Octanoic acid 

Downstream Products

• 40843-12-7 4-(4-Chlorphenoxy)-α-phenoxy-caprylsaeure 
• 51337-96-3 2-[4-(4-Chloro-phenoxy)-phenoxy]-octanoic acid ethyl ester 
• 63538-11-4 2-{4-[4-(1-Ethoxycarbonyl-heptyloxy)-phenylsulfanyl]-phenoxy}-octanoic acid ethyl ester 
• 63538-38-5 2-{4-[4-(1-Ethoxycarbonyl-heptyloxy)-benzenesulfonyl]-phenoxy}-octanoic acid ethyl ester 
• 63538-37-4 2-{4-[4-(1-Ethoxycarbonyl-heptyloxy)-benzenesulfinyl]-phenoxy}-octanoic acid ethyl ester 
• 63538-26-1 2-{2-Chloro-4-[3-chloro-4-(1-ethoxycarbonyl-heptyloxy)-phenoxy]-phenoxy}-octanoic acid ethyl ester 
• 63538-29-4 2-{2-Bromo-4-[3-bromo-4-(1-ethoxycarbonyl-heptyloxy)-phenoxy]-phenoxy}-octanoic acid ethyl ester 
• 63538-28-3 2-{2,6-Dichloro-4-[3,5-dichloro-4-(1-ethoxycarbonyl-heptyloxy)-phenoxy]-phenoxy}-octanoic acid ethyl ester 
• 7597-88-8 2-(1,1,3-trioxo-1,3-dihydro-1λ⁶-benzo[d]isothiazol-2-yl)-octanoic acid ethyl ester 
• 2351-90-8 Ethyl oct-2-enoate 
• 7740-65-0 Ethyl 2-fluorooctanoate 
• 188699-85-6 2-[2-({3-[(E)-2-(7-Chloro-quinolin-2-yl)-vinyl]-phenylamino}-methyl)-phenoxy]-octanoic acid ethyl ester 
• 302571-70-6 ethyl 2-bromo-2-hexyl-3-hydroxy-4-phenylpentanoate 
• 371227-18-8 2-[3-(4-hydroxy-phenyl)-4-oxo-4H-chromen-7-yloxy]-octanoic acid ethyl ester 

Relevant articles and documents

Highly selective synthesis of α-bromoesters using molecular bromine catalyzed by phosphorus

A series of α-bromoesters have been synthesized by applying Hell-Volhard-Zelinsky reaction catalyzed by phosphorus instead of usual phosphorus tribromide. An excellent regioselectivity to good yields are achieved at comparatively mild reaction conditions of an operational simplicity.

SOLVOLYSIS OF 1-CHLORO-1-ALKENYL PHENYL SULFIDES. SYNTHESIS OF α-BROMO PHENYL THIOCARBOXYLIC ESTERS, α-BROMO ALKYL CARBOXYLIC ESTERS AND α-PHENYLTHIO METHYL CARBOXYLIC ESTERS

1-Chloro-1-alkenyl phenyl sulfides treated with bromine followed by hydrolysis or methanolysis give α-bromo phenyl thiocarboxylic esters and α-phenylthio methyl carboxylic esters.Direct oxidative solvolysis with bromine and alcohol give α-bromo alkyl carboxylic esters.

Amino phosphonic acids. II. Aminoalkylphosphonic acids.

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