5466-90-0

Usage

Chemical Properties

White Cyrstalline Solid

InChI:InChI=1/C12H11NO4/c1-8(14)17-7-6-13-11(15)9-4-2-3-5-10(9)12(13)16/h2-5H,6-7H2,1H3

Upstream product

• 1120-64-5 2-methyl-4,5-dihydro-1,3-oxazole 
• 85-44-9 phthalic anhydride 
• 3891-07-4 N-(2-Hydroxyethyl)phthalimide 
• 108-24-7 acetic anhydride 
• 574-98-1 2-(2-bromoethyl)isoindoline-1,3-dione 
• 20583-42-0 acetic acid-(2-phthalimido-vinyl ester) 
• 2466-76-4 N-Acetylimidazole 
• 123-91-1 1,4-dioxane 
• 506-96-7 Acetyl bromide 
• 141-78-6 ethyl acetate 
• 20622-86-0 N-(1,2-Dibromethyl)phthalimid 
• 55694-50-3 N-(2-tetrahydropyran-2-yloxy-ethyl)-phthalimide 
• 20583-41-9 N-(1,2-diacetoxy-ethyl)-phthalimide 

Downstream Products

• 3485-84-5 N-vinylphthalimide 

Relevant academic research and scientific papers

One-step transformation of tetrahydropyranyl ethers using indium(III) triflate as the catalyst

A convergent one-step transformation of tetrahydropyranyl (THP) ethers is described. According to our earlier experiments, indium(III) triflate has proven to be an efficient catalyst for the transformation of THP ethers into their corresponding acetates.

Ruthenium(III) acetylacetonate [Ru(acac)3] -An efficient recyclable catalyst for the acetylation of phenols, alcohols, and amines under neat conditions

A catalytic amount of ruthenium(III) acetylacetonate (2 mol%) [Ru(acac)3] enables solvent-free acetylation of phenols, alcohols, and amines at ambient temperature in good to excellent yields. Furthermore, the catalyst could be recovered and reused at least three times without a significant loss in yields.

Transesterification of α-substituted esters mediated by potassium carbonate

α-Substituted esters were efficiently and easily transesterificated at room temperature in the presence of potassium carbonate. α-Halo esters can be transesterificated without substitution of the halogen atom.

Synthesis of acetoxyamides and acetates by zinc bromide assisted cleavage of Merrifield resin-bound ethers

A new method for the synthesis of acetoxyamides and acetates using Merrifield resin is described. The method uses zinc bromide to promote the conversion of Merrifield resin-bound ethers to acetates under ambient conditions. The cleavage products obtained are of high yields and chemical purity.

Solid state acetylation with acetylimidazole: Selective protection of primary alcohols and phenols

Primary alcohols and phenols have been acetylated with acetylimidazole by the solid state reaction, grinding both substrates with a pestle in a mortar.