54985-33-0

Basic information

• Product Name: cis-1-(n-Hexyl-1-hydroxy-4-phenyl)-3-buten
• CAS NO: 54985-33-0
• Molecular Weight: 232.366
• Mol File: 54985-33-0.mol

Chemical Properties

• CAS DataBase Reference: cis-1-(n-Hexyl-1-hydroxy-4-phenyl)-3-buten(CAS DataBase Reference)
• NIST Chemistry Reference: cis-1-(n-Hexyl-1-hydroxy-4-phenyl)-3-buten(54985-33-0)
• EPA Substance Registry System: cis-1-(n-Hexyl-1-hydroxy-4-phenyl)-3-buten(54985-33-0)

Safety Data

• Hazardous Substances Data: 54985-33-0(Hazardous Substances Data)

Upstream product

• 110792-92-2 1-[(E)-dec-3-en-1-ynyl]benzene 
• 536-74-3 phenylacetylene 
• 42599-17-7 (E)-1-iodo-1-octene 
• 111-71-7 heptanal 
• 74785-32-3 (E)-cinnamyl(tributyl)tin 

Relevant articles and documents

Stereoselective Traceless Borylation–Allenation of Propargylic Epoxides: Dual Role of the Copper Catalyst

Chiral α-allenols are prepared with high diastereocontrol through an unprecedented and spontaneous β-oxygen elimination of an α-epoxy vinyl boronate. Stochiometric experiments and DFT calculations support a dual role of the copper catalyst, which orchestrates the hydroboration and the syn-elimination step.

On the Transmetallation of (E)-1-Phenyl-3-(tributylstannyl)propene and 3-Phenyl-3-(tributylstannyl)propene with BuSnCl3

Transmetallation of (E)-1-phenyl-3-(tributylstannyl)propene and 3-phenyl-3-(tributylstannyl)propene with BuSnCl3, and the isomerization of the transmetallated product are described.The application of the reactions to stereoselective (Z)-3-phenyl-2-propenylation and threo-1-phenyl-2-propenylation of aldehydes is also described.